Insight into the mechanism of the Saegusa oxidation: Isolation of a novel palladium(0)-tetraolefin complex

Stefanie Porth, Jan W. Bats, Dirk Trauner, Gerald Giester, Johann Mulzer

Research output: Contribution to journalArticle

Abstract

As an intermediate of the Saegusa oxidation of the silyl enol ether 1, the novel, structurally highly unusual d10 Pd0-tetraolefin complex 2 was isolated; 2 is the first complex of this type whose solid-state geometry has been fully elucidated. Apparently, the enone formed in the course of the reaction is conformationally preorganized to act as a host for the palladium atom. TMS=trimethylsilyl.

Original languageEnglish (US)
Pages (from-to)2015-2016
Number of pages2
JournalAngewandte Chemie - International Edition
Volume38
Issue number13-14
StatePublished - Jul 12 1999

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Palladium
Ether
Ethers
Atoms
Oxidation
Geometry

Keywords

  • Alkene complexes
  • Enones
  • Oxidations
  • Palladium
  • Silyl enol ethers

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

Cite this

Insight into the mechanism of the Saegusa oxidation : Isolation of a novel palladium(0)-tetraolefin complex. / Porth, Stefanie; Bats, Jan W.; Trauner, Dirk; Giester, Gerald; Mulzer, Johann.

In: Angewandte Chemie - International Edition, Vol. 38, No. 13-14, 12.07.1999, p. 2015-2016.

Research output: Contribution to journalArticle

Porth, S, Bats, JW, Trauner, D, Giester, G & Mulzer, J 1999, 'Insight into the mechanism of the Saegusa oxidation: Isolation of a novel palladium(0)-tetraolefin complex', Angewandte Chemie - International Edition, vol. 38, no. 13-14, pp. 2015-2016.
Porth, Stefanie ; Bats, Jan W. ; Trauner, Dirk ; Giester, Gerald ; Mulzer, Johann. / Insight into the mechanism of the Saegusa oxidation : Isolation of a novel palladium(0)-tetraolefin complex. In: Angewandte Chemie - International Edition. 1999 ; Vol. 38, No. 13-14. pp. 2015-2016.
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