Infrared hole burning and conformational change in a borane - Ammonia complex

Christopher A. Endicott, Herbert L. Strauss, Chambers C. Hughes, Dirk Trauner

Research output: Contribution to journalArticle

Abstract

The N-D stretching region in the infrared spectrum of the ammonia complex of tris-(2-methoxymethylphenol)-borane containing one D atom has been examined. The N-D bands have been hole burned, and the resulting spectra reveal the reorientation kinetics of the ammonia. The ammonia is hydrogen bonded with the bond distances and reorientation barrier typical of other compounds. The N-D stretching frequencies are higher than those of comparison compounds.

Original languageEnglish (US)
Pages (from-to)7714-7717
Number of pages4
JournalJournal of Physical Chemistry A
Volume109
Issue number34
DOIs
StatePublished - Sep 1 2005

Fingerprint

Boranes
boranes
hole burning
Ammonia
ammonia
Infrared radiation
Stretching
retraining
Hydrogen
infrared spectra
Atoms
Kinetics
kinetics
hydrogen
atoms

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Endicott, C. A., Strauss, H. L., Hughes, C. C., & Trauner, D. (2005). Infrared hole burning and conformational change in a borane - Ammonia complex. Journal of Physical Chemistry A, 109(34), 7714-7717. https://doi.org/10.1021/jp051969i

Infrared hole burning and conformational change in a borane - Ammonia complex. / Endicott, Christopher A.; Strauss, Herbert L.; Hughes, Chambers C.; Trauner, Dirk.

In: Journal of Physical Chemistry A, Vol. 109, No. 34, 01.09.2005, p. 7714-7717.

Research output: Contribution to journalArticle

Endicott, CA, Strauss, HL, Hughes, CC & Trauner, D 2005, 'Infrared hole burning and conformational change in a borane - Ammonia complex', Journal of Physical Chemistry A, vol. 109, no. 34, pp. 7714-7717. https://doi.org/10.1021/jp051969i
Endicott, Christopher A. ; Strauss, Herbert L. ; Hughes, Chambers C. ; Trauner, Dirk. / Infrared hole burning and conformational change in a borane - Ammonia complex. In: Journal of Physical Chemistry A. 2005 ; Vol. 109, No. 34. pp. 7714-7717.
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