Imaging enhanced energy transfer in a levitated aerosol particle

S. Arnold, S. Holler, S. D. Druger

Research output: Contribution to journalArticle

Abstract

Energy transfer experiments are carried out at dilute concentrations of donors (10 -4 M, coumarine 334) and acceptors (5×10 -6 M, sulforhodamine 101) in a levitated microdroplet (diameter, 2a = 19 μm), using an aerosol particle fluorescence microscope. Microphotographs in donor and acceptor luminescence show that the transfer mechanism is not of a Förster type, but is mediated by morphology dependent resonances (MDRs) of the microdroplet. The transfer is vanishingly small in the central region of the droplet (r<0.9a), and grows to a pronounced maximum beneath the surface (active region), consistent with the theory of MDR-enhanced energy transfer. The angular intensity profile of the acceptor image, along with current theory, suggests that the energy transfer is a maximum with the donor and acceptor at equal distances on opposite sides of the droplet center, ∼18 μm apart. From photometry we measure an overall ratio of acceptor to total luminescence of 7%. Within the active region the transfer efficiency is above 50%. This yield is ∼1000× that expected from Förster transfer. This effect may be understood from a modification in the photon density of states in this region, which leads to efficient photon emission into MDRs.

Original languageEnglish (US)
Pages (from-to)7741-7747
Number of pages7
JournalJournal of Chemical Physics
Volume104
Issue number19
StatePublished - 1996

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Aerosols
Energy transfer
aerosols
energy transfer
Imaging techniques
Luminescence
Photons
Coumarins
Photometry
microphotographs
luminescence
photon density
Microscopes
Fluorescence
photometry
microscopes
fluorescence
photons
profiles
Experiments

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

Imaging enhanced energy transfer in a levitated aerosol particle. / Arnold, S.; Holler, S.; Druger, S. D.

In: Journal of Chemical Physics, Vol. 104, No. 19, 1996, p. 7741-7747.

Research output: Contribution to journalArticle

Arnold, S, Holler, S & Druger, SD 1996, 'Imaging enhanced energy transfer in a levitated aerosol particle', Journal of Chemical Physics, vol. 104, no. 19, pp. 7741-7747.
Arnold, S. ; Holler, S. ; Druger, S. D. / Imaging enhanced energy transfer in a levitated aerosol particle. In: Journal of Chemical Physics. 1996 ; Vol. 104, No. 19. pp. 7741-7747.
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