High-resolution analysis of the kinetic energy distribution of fragment ions produced by dissociative ionization of propane

T. Fiegele, C. Mair, P. Scheier, K. Becker, T. D. Märk

Research output: Contribution to journalArticle

Abstract

We report measurements of the kinetic energy distributions of fragment ions produced by electron impact dissociative ionization of propane using a two-sector-field mass spectrometer in conjunction with the retarding field method. This technique achieves a higher energy resolution, albeit at much reduced ion signals and at a significant loss of energetic fragment ions compared to the conventional ion deflection technique, which has been used extensively by other groups in the past. The higher energy resolution used in the present experiments results in a complete separation of the thermal/quasi-thermal fragment ions from the energetic fragment ions. This, in turn, reveals that the energetic fragment ions have a much narrower kinetic energy distribution than previously assumed. Because of the comparatively weak ion signals, further studies such as separate threshold cross-section measurements and appearance energy determinations for, respectively, the "slow" and "fast" fragment ions could only be carried out for the CH3 + and C2H4 + fragment ions.

Original languageEnglish (US)
Pages (from-to)145-152
Number of pages8
JournalInternational Journal of Mass Spectrometry
Volume207
Issue number3
DOIs
StatePublished - May 16 2001

Fingerprint

Propane
propane
Kinetic energy
Ionization
energy distribution
kinetic energy
fragments
Ions
ionization
high resolution
ions
Impact ionization
Mass spectrometers
mass spectrometers
electron impact
energy
deflection
sectors
retarding

Keywords

  • Electron-impact ionization
  • Hydrocarbons
  • Kinetic energy distributions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy

Cite this

High-resolution analysis of the kinetic energy distribution of fragment ions produced by dissociative ionization of propane. / Fiegele, T.; Mair, C.; Scheier, P.; Becker, K.; Märk, T. D.

In: International Journal of Mass Spectrometry, Vol. 207, No. 3, 16.05.2001, p. 145-152.

Research output: Contribution to journalArticle

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AU - Mair, C.

AU - Scheier, P.

AU - Becker, K.

AU - Märk, T. D.

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N2 - We report measurements of the kinetic energy distributions of fragment ions produced by electron impact dissociative ionization of propane using a two-sector-field mass spectrometer in conjunction with the retarding field method. This technique achieves a higher energy resolution, albeit at much reduced ion signals and at a significant loss of energetic fragment ions compared to the conventional ion deflection technique, which has been used extensively by other groups in the past. The higher energy resolution used in the present experiments results in a complete separation of the thermal/quasi-thermal fragment ions from the energetic fragment ions. This, in turn, reveals that the energetic fragment ions have a much narrower kinetic energy distribution than previously assumed. Because of the comparatively weak ion signals, further studies such as separate threshold cross-section measurements and appearance energy determinations for, respectively, the "slow" and "fast" fragment ions could only be carried out for the CH3 + and C2H4 + fragment ions.

AB - We report measurements of the kinetic energy distributions of fragment ions produced by electron impact dissociative ionization of propane using a two-sector-field mass spectrometer in conjunction with the retarding field method. This technique achieves a higher energy resolution, albeit at much reduced ion signals and at a significant loss of energetic fragment ions compared to the conventional ion deflection technique, which has been used extensively by other groups in the past. The higher energy resolution used in the present experiments results in a complete separation of the thermal/quasi-thermal fragment ions from the energetic fragment ions. This, in turn, reveals that the energetic fragment ions have a much narrower kinetic energy distribution than previously assumed. Because of the comparatively weak ion signals, further studies such as separate threshold cross-section measurements and appearance energy determinations for, respectively, the "slow" and "fast" fragment ions could only be carried out for the CH3 + and C2H4 + fragment ions.

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