From nuclear structure to the quadrupolar NMR interaction and high-resolution spectroscopy

Research output: Contribution to journalArticle

Abstract

The relation of nuclear physics with quadrupolar NMR interaction and high-resolution spectroscopy is discussed. The nuclear structure and spin, nucleus-electron interaction, quantum nucleus-electron interaction and the ionic model for electric field gradients, Sternheimer factor are also discussed. The appearance of spectra under the action of the quarupolar NMR Hamiltonian which include, first- and second-order effects, the nuclear quadrupole resonance, and cross-terms with the dipolar and chemical shift anisotropy interactions, are also discussed. The high-resolution techniques such as, double rotation, dynamic-angle spinning, multiple-quantum magic-angle spinning, and satellite transition magic-angle spinning.

Original languageEnglish (US)
Pages (from-to)63-78
Number of pages16
JournalProgress in Nuclear Magnetic Resonance Spectroscopy
Volume46
Issue number1
DOIs
StatePublished - Mar 17 2005

Fingerprint

Magic angle spinning
nuclear structure
metal spinning
Spectrum Analysis
Nuclear Physics
Nuclear magnetic resonance
Nuclear quadrupole resonance
Spectroscopy
Electrons
Hamiltonians
Nuclear physics
nuclear magnetic resonance
high resolution
Anisotropy
electron scattering
Chemical shift
spectroscopy
nuclei
nuclear quadrupole resonance
Electric fields

Keywords

  • DAS
  • DOR
  • Electric field gradient
  • MQMAS
  • NQR
  • Nuclear quadrupole moment
  • Nuclear structure and spin
  • Quadrupolar coupling
  • Solid-state NMR
  • STMAS

ASJC Scopus subject areas

  • Spectroscopy
  • Radiology Nuclear Medicine and imaging
  • Condensed Matter Physics

Cite this

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abstract = "The relation of nuclear physics with quadrupolar NMR interaction and high-resolution spectroscopy is discussed. The nuclear structure and spin, nucleus-electron interaction, quantum nucleus-electron interaction and the ionic model for electric field gradients, Sternheimer factor are also discussed. The appearance of spectra under the action of the quarupolar NMR Hamiltonian which include, first- and second-order effects, the nuclear quadrupole resonance, and cross-terms with the dipolar and chemical shift anisotropy interactions, are also discussed. The high-resolution techniques such as, double rotation, dynamic-angle spinning, multiple-quantum magic-angle spinning, and satellite transition magic-angle spinning.",
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