Enantiomer-specific oriented attachment

Formation of macroscopic homochiral crystal aggregates from a racemic system

Cristóbal Viedma, J. Michael McBride, Bart Kahr, Pedro Cintas

Research output: Contribution to journalArticle

Abstract

Let's get together: Racemic samples of d- and l-enantiomorphous NaBrO 3 (or NaClO3) crystals aggregate with nearly complete enantioselection. Centimeter-sized enantiopure megacrystals are often produced, and these can be sorted easily.

Original languageEnglish (US)
Pages (from-to)10545-10548
Number of pages4
JournalAngewandte Chemie - International Edition
Volume52
Issue number40
DOIs
StatePublished - Sep 27 2013

Fingerprint

Enantiomers
Crystals

Keywords

  • alignment mechanism
  • chirality
  • crystal growth
  • enantioselection
  • oriented attachment

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Enantiomer-specific oriented attachment : Formation of macroscopic homochiral crystal aggregates from a racemic system. / Viedma, Cristóbal; McBride, J. Michael; Kahr, Bart; Cintas, Pedro.

In: Angewandte Chemie - International Edition, Vol. 52, No. 40, 27.09.2013, p. 10545-10548.

Research output: Contribution to journalArticle

@article{1e6b66e660da4f11a58e857c9f3eaea6,
title = "Enantiomer-specific oriented attachment: Formation of macroscopic homochiral crystal aggregates from a racemic system",
abstract = "Let's get together: Racemic samples of d- and l-enantiomorphous NaBrO 3 (or NaClO3) crystals aggregate with nearly complete enantioselection. Centimeter-sized enantiopure megacrystals are often produced, and these can be sorted easily.",
keywords = "alignment mechanism, chirality, crystal growth, enantioselection, oriented attachment",
author = "Crist{\'o}bal Viedma and McBride, {J. Michael} and Bart Kahr and Pedro Cintas",
year = "2013",
month = "9",
day = "27",
doi = "10.1002/anie.201303915",
language = "English (US)",
volume = "52",
pages = "10545--10548",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "40",

}

TY - JOUR

T1 - Enantiomer-specific oriented attachment

T2 - Formation of macroscopic homochiral crystal aggregates from a racemic system

AU - Viedma, Cristóbal

AU - McBride, J. Michael

AU - Kahr, Bart

AU - Cintas, Pedro

PY - 2013/9/27

Y1 - 2013/9/27

N2 - Let's get together: Racemic samples of d- and l-enantiomorphous NaBrO 3 (or NaClO3) crystals aggregate with nearly complete enantioselection. Centimeter-sized enantiopure megacrystals are often produced, and these can be sorted easily.

AB - Let's get together: Racemic samples of d- and l-enantiomorphous NaBrO 3 (or NaClO3) crystals aggregate with nearly complete enantioselection. Centimeter-sized enantiopure megacrystals are often produced, and these can be sorted easily.

KW - alignment mechanism

KW - chirality

KW - crystal growth

KW - enantioselection

KW - oriented attachment

UR - http://www.scopus.com/inward/record.url?scp=84884882839&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84884882839&partnerID=8YFLogxK

U2 - 10.1002/anie.201303915

DO - 10.1002/anie.201303915

M3 - Article

VL - 52

SP - 10545

EP - 10548

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 40

ER -