Abstract
A report is presented on results from the author's initial investigations of the synthesis, structure, and physical characterization of charge transfer solids derived from these cations and the TCNQ- and C3[C(CN)2]3 - polycyanoanions. The solid-state motifs of the acceptor anion stacks and the molecular stoichiometry of the complexes are governed by the spatial orientation of charges in interactions and electronic properties of these materials. The charge transfer complexes described clearly demonstrate that the three-dimensional solid-state structure can be rationally controlled by designed electrostatic interactions between polycations of known dimensionality and planar acceptor anions. The stoichiometry of charge transfer complexes and the degree of charge on molecular components can be rationally controlled by the charge and size (length) of the polycation, as well as by the electrochemical parameters during electrocrystallization of these complexes.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1719-1732 |
| Number of pages | 14 |
| Journal | Journal of the American Chemical Society |
| Volume | 111 |
| Issue number | 5 |
| State | Published - Mar 1 1989 |
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ASJC Scopus subject areas
- Chemistry(all)
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Electrostatic structural enforcement in low-dimensional solids : Synthesis, structure, and electronic properties of polycationic ruthenium complexes with polycyanoanions. / Ward, Michael; Fagan, Paul J.; Calabrese, Joseph C.; Johnson, David C.
In: Journal of the American Chemical Society, Vol. 111, No. 5, 01.03.1989, p. 1719-1732.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Electrostatic structural enforcement in low-dimensional solids
T2 - Synthesis, structure, and electronic properties of polycationic ruthenium complexes with polycyanoanions
AU - Ward, Michael
AU - Fagan, Paul J.
AU - Calabrese, Joseph C.
AU - Johnson, David C.
PY - 1989/3/1
Y1 - 1989/3/1
N2 - A report is presented on results from the author's initial investigations of the synthesis, structure, and physical characterization of charge transfer solids derived from these cations and the TCNQ- and C3[C(CN)2]3 - polycyanoanions. The solid-state motifs of the acceptor anion stacks and the molecular stoichiometry of the complexes are governed by the spatial orientation of charges in interactions and electronic properties of these materials. The charge transfer complexes described clearly demonstrate that the three-dimensional solid-state structure can be rationally controlled by designed electrostatic interactions between polycations of known dimensionality and planar acceptor anions. The stoichiometry of charge transfer complexes and the degree of charge on molecular components can be rationally controlled by the charge and size (length) of the polycation, as well as by the electrochemical parameters during electrocrystallization of these complexes.
AB - A report is presented on results from the author's initial investigations of the synthesis, structure, and physical characterization of charge transfer solids derived from these cations and the TCNQ- and C3[C(CN)2]3 - polycyanoanions. The solid-state motifs of the acceptor anion stacks and the molecular stoichiometry of the complexes are governed by the spatial orientation of charges in interactions and electronic properties of these materials. The charge transfer complexes described clearly demonstrate that the three-dimensional solid-state structure can be rationally controlled by designed electrostatic interactions between polycations of known dimensionality and planar acceptor anions. The stoichiometry of charge transfer complexes and the degree of charge on molecular components can be rationally controlled by the charge and size (length) of the polycation, as well as by the electrochemical parameters during electrocrystallization of these complexes.
UR - http://www.scopus.com/inward/record.url?scp=0024621413&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0024621413&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0024621413
VL - 111
SP - 1719
EP - 1732
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 5
ER -