Electron-transfer studies at YBa2Cu3O7, Bi2Sr2.2Ca0.8Ca2O8, and Tl2Ba2Ca2Cu3O10

John McDevitt, Robin L. McCarley, E. F. Dalton, R. Gollmar, Royce W. Murray, James Collman, Gordon T. Yee, William A. Little

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

We have developed the methodology for fabricating well behaved electrodes utilizing high temperature superconductors YBa2Cu3 O7 (Tc=94K), Bi2Sr2.2Ca0.8(Tc=90K) and Tl2Ba2Ca2Cu3O10(Tc=112K). Electrochemical corrosion studies have been completed with these electrodes and relative reactivity with water of each phase has been assessed. Freshly surfaced electrodes display facile room temperature electron transfer between superconductor phases and both solution redox species and surface confined electroactive polymers. This work should lay the grounds for construction of novel molecular film/ superconductor junctions which can be studied at a variety of temperatures.

Original languageEnglish (US)
Title of host publicationACS Symposium Series
Pages207-222
Number of pages16
Edition377
StatePublished - 1988
EventChemistry of High-Temperature Superconductors II - Los Angeles, CA, USA
Duration: Sep 25 1988Sep 30 1988

Other

OtherChemistry of High-Temperature Superconductors II
CityLos Angeles, CA, USA
Period9/25/889/30/88

Fingerprint

Superconducting materials
Electrodes
Electrons
Electrochemical corrosion
High temperature superconductors
Electron temperature
Polymers
Water
barium copper yttrium oxide
Temperature
Oxidation-Reduction

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

McDevitt, J., McCarley, R. L., Dalton, E. F., Gollmar, R., Murray, R. W., Collman, J., ... Little, W. A. (1988). Electron-transfer studies at YBa2Cu3O7, Bi2Sr2.2Ca0.8Ca2O8, and Tl2Ba2Ca2Cu3O10. In ACS Symposium Series (377 ed., pp. 207-222)

Electron-transfer studies at YBa2Cu3O7, Bi2Sr2.2Ca0.8Ca2O8, and Tl2Ba2Ca2Cu3O10. / McDevitt, John; McCarley, Robin L.; Dalton, E. F.; Gollmar, R.; Murray, Royce W.; Collman, James; Yee, Gordon T.; Little, William A.

ACS Symposium Series. 377. ed. 1988. p. 207-222.

Research output: Chapter in Book/Report/Conference proceedingChapter

McDevitt, J, McCarley, RL, Dalton, EF, Gollmar, R, Murray, RW, Collman, J, Yee, GT & Little, WA 1988, Electron-transfer studies at YBa2Cu3O7, Bi2Sr2.2Ca0.8Ca2O8, and Tl2Ba2Ca2Cu3O10. in ACS Symposium Series. 377 edn, pp. 207-222, Chemistry of High-Temperature Superconductors II, Los Angeles, CA, USA, 9/25/88.
McDevitt J, McCarley RL, Dalton EF, Gollmar R, Murray RW, Collman J et al. Electron-transfer studies at YBa2Cu3O7, Bi2Sr2.2Ca0.8Ca2O8, and Tl2Ba2Ca2Cu3O10. In ACS Symposium Series. 377 ed. 1988. p. 207-222
McDevitt, John ; McCarley, Robin L. ; Dalton, E. F. ; Gollmar, R. ; Murray, Royce W. ; Collman, James ; Yee, Gordon T. ; Little, William A. / Electron-transfer studies at YBa2Cu3O7, Bi2Sr2.2Ca0.8Ca2O8, and Tl2Ba2Ca2Cu3O10. ACS Symposium Series. 377. ed. 1988. pp. 207-222
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AU - Dalton, E. F.

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AU - Yee, Gordon T.

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