Direct observation of mixing of spin multiplets in an antiferromagnetic molecular nanomagnet by electron paramagnetic resonance

S. Datta, O. Waldmann, A. D. Kent, V. A. Milway, L. K. Thompson, S. Hill

    Research output: Contribution to journalArticle

    Abstract

    High-frequency electron paramagnetic resonance (EPR) studies of the antiferromagnetic Mn-[3×3] molecular grid clearly reveal a breaking of the ΔS=0 selection rule, providing direct evidence for the mixing of spin wave functions (S mixing) induced by the comparable exchange and magnetoanisotropy energy scales within the grid. This finding highlights the potential utility of EPR for studies of exchange splittings in molecular nanomagnets, which is normally considered the sole domain of inelastic neutron scattering, thereby offering improved sensitivity and energy resolution.

    Original languageEnglish (US)
    Article number052407
    JournalPhysical Review B - Condensed Matter and Materials Physics
    Volume76
    Issue number5
    DOIs
    StatePublished - Aug 16 2007

    Fingerprint

    Paramagnetic resonance
    electron paramagnetic resonance
    fine structure
    grids
    Inelastic neutron scattering
    Spin waves
    Wave functions
    magnons
    inelastic scattering
    neutron scattering
    wave functions
    energy
    sensitivity

    ASJC Scopus subject areas

    • Condensed Matter Physics

    Cite this

    Direct observation of mixing of spin multiplets in an antiferromagnetic molecular nanomagnet by electron paramagnetic resonance. / Datta, S.; Waldmann, O.; Kent, A. D.; Milway, V. A.; Thompson, L. K.; Hill, S.

    In: Physical Review B - Condensed Matter and Materials Physics, Vol. 76, No. 5, 052407, 16.08.2007.

    Research output: Contribution to journalArticle

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    AU - Thompson, L. K.

    AU - Hill, S.

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