Direct Observation of Asphaltene Nanoparticles on Model Mineral Substrates

Gijo Raj, Alain Lesimple, Jamie Whelan, Pance Naumov

Research output: Contribution to journalArticle

Abstract

The propensity for adherence to solid surfaces of asphaltenes, a complex solubility class of heteropolycyclic aromatic compounds from the heavy fraction of crude oil, has long been the root cause of scale deposition and remains an intractable problem in the petroleum industry. Although the adhesion is essential to understanding the process of asphaltene deposition, the relationship between the conformation of asphaltene molecules on mineral substrates and its impact on adhesion and mechanical properties of the deposits is not completely understood. To rationalize the primary processes in the process of organic scale deposition, here we use atomic force microscopy (AFM) to visualize the morphology of petroleum asphaltenes deposited on model mineral substrates. High imaging contrast was achieved by the differential adhesion of the tip between asphaltenes and the mineral substrate. While asphaltenes form smooth continuous films on all substrates at higher concentrations, they deposit as individual nanoparticles at lower concentrations. The size, shape, and spatial distribution of the nanoaggregates are strongly affected by the nature of the substrate; while uniformly distributed spherical particles are formed on highly polar and hydrophilic substrates (mica), irregular islands and thicker patches are observed with substrates of lower polarity (silica and calcite). Asphaltene nanoparticles flatten when adsorbed on highly oriented pyrolytic graphite due to π-π interactions with the polycyclic core. Force-distance profiles provide direct evidence of the conformational changes of asphaltene molecules on hydrophilic/hydrophobic substrates that result in dramatic changes in adhesion and mechanical properties of asphaltene deposits. Such an understanding of the nature of adhesion and mechanical properties tuned by surface properties, on the level of asphaltene nanoaggregates, would contribute to the design of efficient asphaltene inhibitors for preventing asphaltene fouling on targeted surfaces. Unlike flat surfaces, the AFM phase contrast images of defected calcite surfaces show that asphaltenes form continuous deposits to fill the recesses, and this process could trigger the onset for asphaltene deposition.

Original languageEnglish (US)
Pages (from-to)6248-6257
Number of pages10
JournalLangmuir
Volume33
Issue number25
DOIs
StatePublished - Jun 27 2017

Fingerprint

Minerals
asphaltenes
Asphaltenes
minerals
Nanoparticles
nanoparticles
Substrates
adhesion
Adhesion
Deposits
crude oil
deposits
Calcite
mechanical properties
Calcium Carbonate
calcite
Petroleum
Mechanical properties
Atomic force microscopy
Crude oil

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

Cite this

Direct Observation of Asphaltene Nanoparticles on Model Mineral Substrates. / Raj, Gijo; Lesimple, Alain; Whelan, Jamie; Naumov, Pance.

In: Langmuir, Vol. 33, No. 25, 27.06.2017, p. 6248-6257.

Research output: Contribution to journalArticle

Raj, Gijo ; Lesimple, Alain ; Whelan, Jamie ; Naumov, Pance. / Direct Observation of Asphaltene Nanoparticles on Model Mineral Substrates. In: Langmuir. 2017 ; Vol. 33, No. 25. pp. 6248-6257.
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