Diastereoselective peroxidation of derivatives of Baylis–Hillman adducts

Dylan S. Zuckerman, Keith Woerpel

Research output: Contribution to journalArticle

Abstract

Cyclic derivatives of Baylis–Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.

Original languageEnglish (US)
JournalTetrahedron
DOIs
StatePublished - Jan 1 2019

Fingerprint

Peroxides
Lactones
Cobalt
Derivatives

Keywords

  • Catalysis
  • Cobalt
  • Diastereoselective
  • Peroxide
  • Radical

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Diastereoselective peroxidation of derivatives of Baylis–Hillman adducts. / Zuckerman, Dylan S.; Woerpel, Keith.

In: Tetrahedron, 01.01.2019.

Research output: Contribution to journalArticle

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keywords = "Catalysis, Cobalt, Diastereoselective, Peroxide, Radical",
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KW - Peroxide

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