Diaquabis (4,4′-bipyridine)copper(II) di(o-sulfobenzimidate dichloromethane solvate, a two-dimensional Cu4 (4,4′-C5H4 NC5H4N)4 rhombic grid clathrating guest dichloromethane

Panče Naumov, Gligor Jovanovski, John V. Hanna, Ibrahim Abdul Razak, Suchada Chantrapromma, Hoong Kun Fun, Seik Weng Ng

Research output: Contribution to journalArticle

Abstract

In the crystal structure of bis(4, 4′-bipyridine)diaquacopper(II) di(o-sulfobenzimidate) dichloromethane solvate, the host polycationic [Cu(4, 4′-C5H4 NC5H4N)2 (H2O)2] rhombic grids stack over each other 8.16 Å apart along the c-axis of the orthorhombic Pbcn unit cell. The Cu4(4, 4′-bpy)4 rhombus clathrating a disordered dichloromethane molecule has a copper atom at the corner and the spacer heterocycle with pyridyl rings twisted by 21.8(2)°, as its side. The anions occupy the space between the layers; the grids interact with each other indirectly through water-anion hydrogen bonds [O···O = 2.766(4); O··· N = 3.061(4) Å]. The structure sets a remarkable example of potentials born by the polyfunctional o-sulfobenzimidate moiety for construction of unusual architectures.

Original languageEnglish (US)
Pages (from-to)766-768
Number of pages3
JournalInorganic Chemistry Communications
Volume4
Issue number12
DOIs
StatePublished - Dec 24 2001

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Keywords

  • Bipyridine
  • Clathrate
  • Host-guest complex
  • Saccharin
  • Spacers
  • X-ray diffraction

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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