Diaquabis (4,4′-bipyridine)copper(II) di(o-sulfobenzimidate dichloromethane solvate, a two-dimensional Cu4 (4,4′-C5H4 NC5H4N)4 rhombic grid clathrating guest dichloromethane

Pance Naumov, Gligor Jovanovski, John V. Hanna, Ibrahim Abdul Razak, Suchada Chantrapromma, Hoong Kun Fun, Seik Weng Ng

Research output: Contribution to journalArticle

Abstract

In the crystal structure of bis(4, 4′-bipyridine)diaquacopper(II) di(o-sulfobenzimidate) dichloromethane solvate, the host polycationic [Cu(4, 4′-C5H4 NC5H4N)2 (H2O)2] rhombic grids stack over each other 8.16 Å apart along the c-axis of the orthorhombic Pbcn unit cell. The Cu4(4, 4′-bpy)4 rhombus clathrating a disordered dichloromethane molecule has a copper atom at the corner and the spacer heterocycle with pyridyl rings twisted by 21.8(2)°, as its side. The anions occupy the space between the layers; the grids interact with each other indirectly through water-anion hydrogen bonds [O···O = 2.766(4); O··· N = 3.061(4) Å]. The structure sets a remarkable example of potentials born by the polyfunctional o-sulfobenzimidate moiety for construction of unusual architectures.

Original languageEnglish (US)
Pages (from-to)766-768
Number of pages3
JournalInorganic Chemistry Communications
Volume4
Issue number12
DOIs
StatePublished - Dec 24 2001

Fingerprint

Methylene Chloride
Dichloromethane
Anions
Copper
Negative ions
grids
anions
copper
spacers
Hydrogen bonds
Crystal structure
hydrogen bonds
Atoms
crystal structure
Molecules
Water
rings
cells
water
atoms

Keywords

  • Bipyridine
  • Clathrate
  • Host-guest complex
  • Saccharin
  • Spacers
  • X-ray diffraction

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Diaquabis (4,4′-bipyridine)copper(II) di(o-sulfobenzimidate dichloromethane solvate, a two-dimensional Cu4 (4,4′-C5H4 NC5H4N)4 rhombic grid clathrating guest dichloromethane. / Naumov, Pance; Jovanovski, Gligor; Hanna, John V.; Razak, Ibrahim Abdul; Chantrapromma, Suchada; Fun, Hoong Kun; Ng, Seik Weng.

In: Inorganic Chemistry Communications, Vol. 4, No. 12, 24.12.2001, p. 766-768.

Research output: Contribution to journalArticle

Naumov, Pance ; Jovanovski, Gligor ; Hanna, John V. ; Razak, Ibrahim Abdul ; Chantrapromma, Suchada ; Fun, Hoong Kun ; Ng, Seik Weng. / Diaquabis (4,4′-bipyridine)copper(II) di(o-sulfobenzimidate dichloromethane solvate, a two-dimensional Cu4 (4,4′-C5H4 NC5H4N)4 rhombic grid clathrating guest dichloromethane. In: Inorganic Chemistry Communications. 2001 ; Vol. 4, No. 12. pp. 766-768.
@article{9c17f3f67cda469a95d03f9f134e2301,
title = "Diaquabis (4,4′-bipyridine)copper(II) di(o-sulfobenzimidate dichloromethane solvate, a two-dimensional Cu4 (4,4′-C5H4 NC5H4N)4 rhombic grid clathrating guest dichloromethane",
abstract = "In the crystal structure of bis(4, 4′-bipyridine)diaquacopper(II) di(o-sulfobenzimidate) dichloromethane solvate, the host polycationic [Cu(4, 4′-C5H4 NC5H4N)2 (H2O)2]∝ rhombic grids stack over each other 8.16 {\AA} apart along the c-axis of the orthorhombic Pbcn unit cell. The Cu4(4, 4′-bpy)4 rhombus clathrating a disordered dichloromethane molecule has a copper atom at the corner and the spacer heterocycle with pyridyl rings twisted by 21.8(2)°, as its side. The anions occupy the space between the layers; the grids interact with each other indirectly through water-anion hydrogen bonds [O···O = 2.766(4); O··· N = 3.061(4) {\AA}]. The structure sets a remarkable example of potentials born by the polyfunctional o-sulfobenzimidate moiety for construction of unusual architectures.",
keywords = "Bipyridine, Clathrate, Host-guest complex, Saccharin, Spacers, X-ray diffraction",
author = "Pance Naumov and Gligor Jovanovski and Hanna, {John V.} and Razak, {Ibrahim Abdul} and Suchada Chantrapromma and Fun, {Hoong Kun} and Ng, {Seik Weng}",
year = "2001",
month = "12",
day = "24",
doi = "10.1016/S1387-7003(01)00325-2",
language = "English (US)",
volume = "4",
pages = "766--768",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier BV",
number = "12",

}

TY - JOUR

T1 - Diaquabis (4,4′-bipyridine)copper(II) di(o-sulfobenzimidate dichloromethane solvate, a two-dimensional Cu4 (4,4′-C5H4 NC5H4N)4 rhombic grid clathrating guest dichloromethane

AU - Naumov, Pance

AU - Jovanovski, Gligor

AU - Hanna, John V.

AU - Razak, Ibrahim Abdul

AU - Chantrapromma, Suchada

AU - Fun, Hoong Kun

AU - Ng, Seik Weng

PY - 2001/12/24

Y1 - 2001/12/24

N2 - In the crystal structure of bis(4, 4′-bipyridine)diaquacopper(II) di(o-sulfobenzimidate) dichloromethane solvate, the host polycationic [Cu(4, 4′-C5H4 NC5H4N)2 (H2O)2]∝ rhombic grids stack over each other 8.16 Å apart along the c-axis of the orthorhombic Pbcn unit cell. The Cu4(4, 4′-bpy)4 rhombus clathrating a disordered dichloromethane molecule has a copper atom at the corner and the spacer heterocycle with pyridyl rings twisted by 21.8(2)°, as its side. The anions occupy the space between the layers; the grids interact with each other indirectly through water-anion hydrogen bonds [O···O = 2.766(4); O··· N = 3.061(4) Å]. The structure sets a remarkable example of potentials born by the polyfunctional o-sulfobenzimidate moiety for construction of unusual architectures.

AB - In the crystal structure of bis(4, 4′-bipyridine)diaquacopper(II) di(o-sulfobenzimidate) dichloromethane solvate, the host polycationic [Cu(4, 4′-C5H4 NC5H4N)2 (H2O)2]∝ rhombic grids stack over each other 8.16 Å apart along the c-axis of the orthorhombic Pbcn unit cell. The Cu4(4, 4′-bpy)4 rhombus clathrating a disordered dichloromethane molecule has a copper atom at the corner and the spacer heterocycle with pyridyl rings twisted by 21.8(2)°, as its side. The anions occupy the space between the layers; the grids interact with each other indirectly through water-anion hydrogen bonds [O···O = 2.766(4); O··· N = 3.061(4) Å]. The structure sets a remarkable example of potentials born by the polyfunctional o-sulfobenzimidate moiety for construction of unusual architectures.

KW - Bipyridine

KW - Clathrate

KW - Host-guest complex

KW - Saccharin

KW - Spacers

KW - X-ray diffraction

UR - http://www.scopus.com/inward/record.url?scp=0035196039&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035196039&partnerID=8YFLogxK

U2 - 10.1016/S1387-7003(01)00325-2

DO - 10.1016/S1387-7003(01)00325-2

M3 - Article

VL - 4

SP - 766

EP - 768

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

IS - 12

ER -