Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature

Kap Soo Cheon, Jonathan V. Selinger, Mark M. Green

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

A theory is developed to explain how the optical activity of polymers composed of mirror-image units depended on enantiomeric excess around the 50/50 racemic point. The theory is generalized to describe the polymers consisting of competing chiral units. The polymer is described by the random-field Ising model, with the quenched random field representing the local chiral bias of each monomer.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherACS
Pages957-958
Number of pages2
Volume41
Edition1
StatePublished - Mar 2000
EventThe San Francisco Meeting - San Francisco, CA, USA
Duration: Mar 26 2000Mar 31 2000

Other

OtherThe San Francisco Meeting
CitySan Francisco, CA, USA
Period3/26/003/31/00

Fingerprint

Polymers
Ising model
Temperature
Mirrors
Monomers

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Cheon, K. S., Selinger, J. V., & Green, M. M. (2000). Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (1 ed., Vol. 41, pp. 957-958). ACS.

Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature. / Cheon, Kap Soo; Selinger, Jonathan V.; Green, Mark M.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 1. ed. ACS, 2000. p. 957-958.

Research output: Chapter in Book/Report/Conference proceedingChapter

Cheon, KS, Selinger, JV & Green, MM 2000, Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature. in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 edn, vol. 41, ACS, pp. 957-958, The San Francisco Meeting, San Francisco, CA, USA, 3/26/00.
Cheon KS, Selinger JV, Green MM. Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 ed. Vol. 41. ACS. 2000. p. 957-958
Cheon, Kap Soo ; Selinger, Jonathan V. ; Green, Mark M. / Designing a helical polymer that reverses handedness at a selected, continuously variable, temperature. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 1. ed. ACS, 2000. pp. 957-958
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