Decomposition of energetic materials by pulsed electrical discharges in gas-bubbled aqueous solutions

Oksana Mozgina, A. Koutsospyros, S. Gershman, A. Belkind, C. Christodoulatos, K. Becker

Research output: Contribution to journalArticle

Abstract

The application of high-voltage pulsed electrical discharges in bubbled water (PDBWs) for the remediation of solutions containing energetic compounds such as RDX, HMX, and TNT was investigated. Using low-energy pulses (∼300 mJ/pulse), it was found that the PDBW was highly selective toward the type of energetic compound. The effects of a catalyst and of the pH value of the solution on the degradation of energetic compounds were also studied. HMX decomposition is most effective when the PDBW is used at low pH under Fenton reaction conditions. The degradation efficiency was higher for oxygen O2 than for argon (Ar) as the bubbled gas.

Original languageEnglish (US)
Pages (from-to)905-910
Number of pages6
JournalIEEE Transactions on Plasma Science
Volume37
Issue number6 PART 1
DOIs
StatePublished - 2009

Fingerprint

HMX
aqueous solutions
decomposition
gases
water
degradation
RDX
trinitrotoluene
pulses
high voltages
argon
catalysts
oxygen
energy

Keywords

  • Destruction of energetic compounds
  • Fenton reaction
  • Pulsed electrical discharges

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Nuclear and High Energy Physics

Cite this

Decomposition of energetic materials by pulsed electrical discharges in gas-bubbled aqueous solutions. / Mozgina, Oksana; Koutsospyros, A.; Gershman, S.; Belkind, A.; Christodoulatos, C.; Becker, K.

In: IEEE Transactions on Plasma Science, Vol. 37, No. 6 PART 1, 2009, p. 905-910.

Research output: Contribution to journalArticle

Mozgina, Oksana ; Koutsospyros, A. ; Gershman, S. ; Belkind, A. ; Christodoulatos, C. ; Becker, K. / Decomposition of energetic materials by pulsed electrical discharges in gas-bubbled aqueous solutions. In: IEEE Transactions on Plasma Science. 2009 ; Vol. 37, No. 6 PART 1. pp. 905-910.
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