Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate

Pance Naumov, Semiha Çakir, Iclal Bulut, Ender Bicer, Osman Çakir, Gligor Jovanovski, Abdul Razak Ibrahim, Anwar Usman, Hoong Kun Fun, Suchada Chantrapromma, Weng Ng Seik

    Research output: Contribution to journalReview article

    Abstract

    In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) Å]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.

    Original languageEnglish (US)
    Pages (from-to)175-176
    Number of pages2
    JournalMain Group Metal Chemistry
    Volume25
    Issue number3
    DOIs
    StatePublished - Jan 1 2002

    Fingerprint

    nicotinamide
    Niacinamide
    Lead
    Crystal structure
    Atoms
    crystal structure
    Molecules
    nitrogen atoms
    molecules
    Hydrogen bonds
    Nitrogen
    Oxygen
    oxygen atoms
    interactions
    hydrogen bonds
    Water
    oxygen
    hydrogen
    cells
    water

    ASJC Scopus subject areas

    • Chemistry(all)
    • Condensed Matter Physics
    • Metals and Alloys
    • Materials Chemistry

    Cite this

    Naumov, P., Çakir, S., Bulut, I., Bicer, E., Çakir, O., Jovanovski, G., ... Seik, W. N. (2002). Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate. Main Group Metal Chemistry, 25(3), 175-176. https://doi.org/10.1515/MGMC.2002.25.3.175

    Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate. / Naumov, Pance; Çakir, Semiha; Bulut, Iclal; Bicer, Ender; Çakir, Osman; Jovanovski, Gligor; Ibrahim, Abdul Razak; Usman, Anwar; Fun, Hoong Kun; Chantrapromma, Suchada; Seik, Weng Ng.

    In: Main Group Metal Chemistry, Vol. 25, No. 3, 01.01.2002, p. 175-176.

    Research output: Contribution to journalReview article

    Naumov, P, Çakir, S, Bulut, I, Bicer, E, Çakir, O, Jovanovski, G, Ibrahim, AR, Usman, A, Fun, HK, Chantrapromma, S & Seik, WN 2002, 'Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate', Main Group Metal Chemistry, vol. 25, no. 3, pp. 175-176. https://doi.org/10.1515/MGMC.2002.25.3.175
    Naumov P, Çakir S, Bulut I, Bicer E, Çakir O, Jovanovski G et al. Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate. Main Group Metal Chemistry. 2002 Jan 1;25(3):175-176. https://doi.org/10.1515/MGMC.2002.25.3.175
    Naumov, Pance ; Çakir, Semiha ; Bulut, Iclal ; Bicer, Ender ; Çakir, Osman ; Jovanovski, Gligor ; Ibrahim, Abdul Razak ; Usman, Anwar ; Fun, Hoong Kun ; Chantrapromma, Suchada ; Seik, Weng Ng. / Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate. In: Main Group Metal Chemistry. 2002 ; Vol. 25, No. 3. pp. 175-176.
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    abstract = "In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) {\AA}]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.",
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    AU - Bulut, Iclal

    AU - Bicer, Ender

    AU - Çakir, Osman

    AU - Jovanovski, Gligor

    AU - Ibrahim, Abdul Razak

    AU - Usman, Anwar

    AU - Fun, Hoong Kun

    AU - Chantrapromma, Suchada

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