Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate

Pance Naumov, Semiha Çakir, Iclal Bulut, Ender Bicer, Osman Çakir, Gligor Jovanovski, Abdul Razak Ibrahim, Anwar Usman, Hoong Kun Fun, Suchada Chantrapromma, Weng Ng Seik

Research output: Contribution to journalReview article

Abstract

In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) Å]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.

Original languageEnglish (US)
Pages (from-to)175-176
Number of pages2
JournalMain Group Metal Chemistry
Volume25
Issue number3
DOIs
StatePublished - Jan 1 2002

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nicotinamide
Niacinamide
Lead
Crystal structure
Atoms
crystal structure
Molecules
nitrogen atoms
molecules
Hydrogen bonds
Nitrogen
Oxygen
oxygen atoms
interactions
hydrogen bonds
Water
oxygen
hydrogen
cells
water

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics
  • Metals and Alloys
  • Materials Chemistry

Cite this

Naumov, P., Çakir, S., Bulut, I., Bicer, E., Çakir, O., Jovanovski, G., ... Seik, W. N. (2002). Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate. Main Group Metal Chemistry, 25(3), 175-176. https://doi.org/10.1515/MGMC.2002.25.3.175

Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate. / Naumov, Pance; Çakir, Semiha; Bulut, Iclal; Bicer, Ender; Çakir, Osman; Jovanovski, Gligor; Ibrahim, Abdul Razak; Usman, Anwar; Fun, Hoong Kun; Chantrapromma, Suchada; Seik, Weng Ng.

In: Main Group Metal Chemistry, Vol. 25, No. 3, 01.01.2002, p. 175-176.

Research output: Contribution to journalReview article

Naumov, P, Çakir, S, Bulut, I, Bicer, E, Çakir, O, Jovanovski, G, Ibrahim, AR, Usman, A, Fun, HK, Chantrapromma, S & Seik, WN 2002, 'Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate', Main Group Metal Chemistry, vol. 25, no. 3, pp. 175-176. https://doi.org/10.1515/MGMC.2002.25.3.175
Naumov, Pance ; Çakir, Semiha ; Bulut, Iclal ; Bicer, Ender ; Çakir, Osman ; Jovanovski, Gligor ; Ibrahim, Abdul Razak ; Usman, Anwar ; Fun, Hoong Kun ; Chantrapromma, Suchada ; Seik, Weng Ng. / Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate. In: Main Group Metal Chemistry. 2002 ; Vol. 25, No. 3. pp. 175-176.
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