Abstract
In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) Å]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 175-176 |
| Number of pages | 2 |
| Journal | Main Group Metal Chemistry |
| Volume | 25 |
| Issue number | 3 |
| DOIs | |
| State | Published - Jan 1 2002 |
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ASJC Scopus subject areas
- Chemistry(all)
- Condensed Matter Physics
- Metals and Alloys
- Materials Chemistry
Cite this
Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate. / Naumov, Pance; Çakir, Semiha; Bulut, Iclal; Bicer, Ender; Çakir, Osman; Jovanovski, Gligor; Ibrahim, Abdul Razak; Usman, Anwar; Fun, Hoong Kun; Chantrapromma, Suchada; Seik, Weng Ng.
In: Main Group Metal Chemistry, Vol. 25, No. 3, 01.01.2002, p. 175-176.Research output: Contribution to journal › Review article
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TY - JOUR
T1 - Crystal structure of di(saccharinato-O)lead(II). Nicotinamide hemihydrate
AU - Naumov, Pance
AU - Çakir, Semiha
AU - Bulut, Iclal
AU - Bicer, Ender
AU - Çakir, Osman
AU - Jovanovski, Gligor
AU - Ibrahim, Abdul Razak
AU - Usman, Anwar
AU - Fun, Hoong Kun
AU - Chantrapromma, Suchada
AU - Seik, Weng Ng
PY - 2002/1/1
Y1 - 2002/1/1
N2 - In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) Å]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.
AB - In the lead disaccharinate-nicotinamide complex, the lead atom is covalently bonded to two carbonyl oxygen atoms. It is coordinated by the bridging nicotinamide molecule through the amido oxygen and pyridyl nitrogen atoms; however, the latter interaction is significantly weak [Pb-N 2.73(1) Å]. The bridging heterocyle links adjacent lead disaccharinate molecules into a chain running along the b-axis of the unit cell. A hydrogen bond connects the lattice water molecule to the negatively-charged imido nitrogen atom of the saccharinato entity of two adjacent lead disaccharinate molecules; the amido group also engages in hydrogen bonding interactions to furnish a layer structure.
UR - http://www.scopus.com/inward/record.url?scp=0036395649&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0036395649&partnerID=8YFLogxK
U2 - 10.1515/MGMC.2002.25.3.175
DO - 10.1515/MGMC.2002.25.3.175
M3 - Review article
AN - SCOPUS:0036395649
VL - 25
SP - 175
EP - 176
JO - Reviews on silicon, germanium, tin and lead compounds
JF - Reviews on silicon, germanium, tin and lead compounds
SN - 0792-1241
IS - 3
ER -