Crystal structure and spectroscopic characterization of lithium saccharinate 11/6 hydrate, a hygroscopic and potentially physiologically active compound

Pance Naumov, Gligor Jovanovski, Slavica Tančeva, Seik Weng Ng

Research output: Contribution to journalArticle

Abstract

The structure of the only structurally yet uncharacterized alkali saccharinate, lithium saccharinate, is reported, together with the infrared spectra of its protonated and partially deuterated analogues. The compound crystallizes as strongly hygroscopic colorless triclinic crystal blocks of a 11/6 hydrate, LiC7H4NO3S·11/6H 2O, space group P1, with unit cell dimensions a = 10.070(1), b = 15.755(2), c = 19.134(2) Å, α = 68.085(2), β = 76.940(2), γ = 84.169(2)°, V = 2743.0(5) Å3 and Z = 12 at T = 200(2) K.

Original languageEnglish (US)
Pages (from-to)454-460
Number of pages7
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume632
Issue number3
DOIs
StatePublished - Feb 27 2006

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Alkalies
Hydrates
Lithium
Crystal structure
Infrared radiation
Crystals

Keywords

  • Lithium
  • Saccharinate

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Crystal structure and spectroscopic characterization of lithium saccharinate 11/6 hydrate, a hygroscopic and potentially physiologically active compound. / Naumov, Pance; Jovanovski, Gligor; Tančeva, Slavica; Ng, Seik Weng.

In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 632, No. 3, 27.02.2006, p. 454-460.

Research output: Contribution to journalArticle

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N2 - The structure of the only structurally yet uncharacterized alkali saccharinate, lithium saccharinate, is reported, together with the infrared spectra of its protonated and partially deuterated analogues. The compound crystallizes as strongly hygroscopic colorless triclinic crystal blocks of a 11/6 hydrate, LiC7H4NO3S·11/6H 2O, space group P1, with unit cell dimensions a = 10.070(1), b = 15.755(2), c = 19.134(2) Å, α = 68.085(2), β = 76.940(2), γ = 84.169(2)°, V = 2743.0(5) Å3 and Z = 12 at T = 200(2) K.

AB - The structure of the only structurally yet uncharacterized alkali saccharinate, lithium saccharinate, is reported, together with the infrared spectra of its protonated and partially deuterated analogues. The compound crystallizes as strongly hygroscopic colorless triclinic crystal blocks of a 11/6 hydrate, LiC7H4NO3S·11/6H 2O, space group P1, with unit cell dimensions a = 10.070(1), b = 15.755(2), c = 19.134(2) Å, α = 68.085(2), β = 76.940(2), γ = 84.169(2)°, V = 2743.0(5) Å3 and Z = 12 at T = 200(2) K.

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