Crystal structure and spectroscopic characterization of lithium saccharinate 11/6 hydrate, a hygroscopic and potentially physiologically active compound

Panče Naumov, Gligor Jovanovski, Slavica Tančeva, Seik Weng Ng

Research output: Contribution to journalArticle

Abstract

The structure of the only structurally yet uncharacterized alkali saccharinate, lithium saccharinate, is reported, together with the infrared spectra of its protonated and partially deuterated analogues. The compound crystallizes as strongly hygroscopic colorless triclinic crystal blocks of a 11/6 hydrate, LiC7H4NO3S·11/6H 2O, space group P1, with unit cell dimensions a = 10.070(1), b = 15.755(2), c = 19.134(2) Å, α = 68.085(2), β = 76.940(2), γ = 84.169(2)°, V = 2743.0(5) Å3 and Z = 12 at T = 200(2) K.

Original languageEnglish (US)
Pages (from-to)454-460
Number of pages7
JournalZeitschrift fur Anorganische und Allgemeine Chemie
Volume632
Issue number3
DOIs
StatePublished - Feb 27 2006

Keywords

  • Lithium
  • Saccharinate

ASJC Scopus subject areas

  • Inorganic Chemistry

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