Covalent and orthogonal multi-functionalization of terpolymers

Si Kyung Yang, Marcus Weck

Research output: Contribution to journalArticle

Abstract

Random poly(norbornene)-based terpolymers containing azide, ketone and maleimide functionalities along the side-chain were synthesized using ring-opening metathesis polymerization. Subsequent side-chain functionalizations were carried out using three distinct reactions: maleimide-thiol coupling, 1,3-dipolar cycloaddition, and hydrazone formation. All investigated functionalization transformations proceed with high fidelity and absolute selectivity under mild reaction conditions.

Original languageEnglish (US)
Pages (from-to)582-585
Number of pages4
JournalSoft Matter
Volume5
Issue number3
DOIs
StatePublished - 2009

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Terpolymers
Hydrazones
hydrazones
Azides
Cycloaddition
metathesis
Ring opening polymerization
cycloaddition
Ketones
Sulfhydryl Compounds
thiols
ketones
polymerization
selectivity
rings
maleimide
2-norbornene

ASJC Scopus subject areas

  • Chemistry(all)
  • Condensed Matter Physics

Cite this

Covalent and orthogonal multi-functionalization of terpolymers. / Yang, Si Kyung; Weck, Marcus.

In: Soft Matter, Vol. 5, No. 3, 2009, p. 582-585.

Research output: Contribution to journalArticle

Yang, Si Kyung ; Weck, Marcus. / Covalent and orthogonal multi-functionalization of terpolymers. In: Soft Matter. 2009 ; Vol. 5, No. 3. pp. 582-585.
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