Cooperative recognition of C60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host

Mourad Elhabiri, Ali Trabolsi, François Cardinali, Uwe Hahn, Anne Marie Albrecht-Gary, Jean François Nierengarten

    Research output: Contribution to journalArticle

    Abstract

    A new fullerene derivative with an ammonium subunit has been prepared. Its ability to form supramolecular complexes with oligophenylenevinylene derivatives bearing one or two crown ether moieties has been evidenced by electrospray mass spectrometry, and UV-visible and luminescence spectroscopy experiments. Interestingly, the assembly of the C60-ammonium cation with the oligophenylenevinylene derivative bearing two crown ether moieties leads to the cooperative formation of the 2:1 complex owing to intramolecular fullerene-fullerene interactions.

    Original languageEnglish (US)
    Pages (from-to)4793-4798
    Number of pages6
    JournalChemistry - A European Journal
    Volume11
    Issue number16
    DOIs
    StatePublished - Aug 5 2005

    Fingerprint

    Crown Ethers
    Fullerenes
    Crown ethers
    Bearings (structural)
    Ammonium Compounds
    Derivatives
    Substrates
    Mass spectrometry
    Cations
    Luminescence
    Positive ions
    Spectroscopy
    Experiments

    Keywords

    • Cooperative phenomena ena
    • Crown compounds
    • Fullerenes
    • pi-conjugated system
    • Supramolecular chemistry

    ASJC Scopus subject areas

    • Chemistry(all)

    Cite this

    Elhabiri, M., Trabolsi, A., Cardinali, F., Hahn, U., Albrecht-Gary, A. M., & Nierengarten, J. F. (2005). Cooperative recognition of C60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host. Chemistry - A European Journal, 11(16), 4793-4798. https://doi.org/10.1002/chem.200500246

    Cooperative recognition of C60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host. / Elhabiri, Mourad; Trabolsi, Ali; Cardinali, François; Hahn, Uwe; Albrecht-Gary, Anne Marie; Nierengarten, Jean François.

    In: Chemistry - A European Journal, Vol. 11, No. 16, 05.08.2005, p. 4793-4798.

    Research output: Contribution to journalArticle

    Elhabiri, M, Trabolsi, A, Cardinali, F, Hahn, U, Albrecht-Gary, AM & Nierengarten, JF 2005, 'Cooperative recognition of C60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host', Chemistry - A European Journal, vol. 11, no. 16, pp. 4793-4798. https://doi.org/10.1002/chem.200500246
    Elhabiri, Mourad ; Trabolsi, Ali ; Cardinali, François ; Hahn, Uwe ; Albrecht-Gary, Anne Marie ; Nierengarten, Jean François. / Cooperative recognition of C60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host. In: Chemistry - A European Journal. 2005 ; Vol. 11, No. 16. pp. 4793-4798.
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