Confined homopolymers

H. L. Frisch, Jerome Percus

Research output: Contribution to journalArticle

Abstract

The equilibrium statistical mechanics of a next-neighbor interacting homopolymer is set up in the grand ensemble of its monomers, as well as that of noninteracting polymers. Expressions for density profile, as well as degree of polymerization and radius of gyration are obtained. Application is made to polymers in a cylindrical enclosure, with an idealized interaction, and the realm of validity of the formalism assessed.

Original languageEnglish (US)
Pages (from-to)11834-11837
Number of pages4
JournalJournal of Physical Chemistry B
Volume105
Issue number47
DOIs
StatePublished - Nov 29 2001

Fingerprint

Homopolymerization
Polymers
Statistical mechanics
gyration
polymers
enclosure
Enclosures
statistical mechanics
polymerization
monomers
Monomers
Polymerization
formalism
radii
profiles
interactions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Frisch, H. L., & Percus, J. (2001). Confined homopolymers. Journal of Physical Chemistry B, 105(47), 11834-11837. https://doi.org/10.1021/jp011885j

Confined homopolymers. / Frisch, H. L.; Percus, Jerome.

In: Journal of Physical Chemistry B, Vol. 105, No. 47, 29.11.2001, p. 11834-11837.

Research output: Contribution to journalArticle

Frisch, HL & Percus, J 2001, 'Confined homopolymers', Journal of Physical Chemistry B, vol. 105, no. 47, pp. 11834-11837. https://doi.org/10.1021/jp011885j
Frisch HL, Percus J. Confined homopolymers. Journal of Physical Chemistry B. 2001 Nov 29;105(47):11834-11837. https://doi.org/10.1021/jp011885j
Frisch, H. L. ; Percus, Jerome. / Confined homopolymers. In: Journal of Physical Chemistry B. 2001 ; Vol. 105, No. 47. pp. 11834-11837.
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