CONDUCTIVE MOLECULAR CRYSTALS. STRUCTURAL, MAGNETIC, AND CHARGE-TRANSPORT PROPERTIES OF (5,10,15,20-TETRAMETHYLPORPHYRINATO)NICKEL(II) IODIDE.

Laurel J. Pace, Jens Martinsen, Abraham Ulman, Brian M. Hoffman, James A. Ibers

Research output: Contribution to journalArticle

Abstract

(5,10,15,20-Tetramethylporphyrinato)nickel(II), Ni(tmp), has been partially oxidized by reaction with iodine. The authors report the structural, magnetic, and charge-transport properties of single crystals of the resulting compound, Ni(tmp)I. The compound crystallizes in space group D//4//h**4-P4/nnc of the tetragonal system with four formula units in a cell of dimensions a equals 16. 610 (15) A and c equals 6. 932 (7) A at 114 K. Full-matrix least-squares refinement of 69 variables gives a final value for the R index on F**2 of 0. 079 for 1418 observations. The structure consists of S//4-ruffled Ni(tmp) molecules, stacked metal-over-metal, with a Ni-Ni spacing along the stack of 3. 466 (3) A. Adjacent Ni(tmp) units in the unit cell are staggered by 37 degree . Severely disordered chains of iodine are located in channels surrounding the Ni(tmp) stacks.

Original languageEnglish (US)
Pages (from-to)2612-2620
Number of pages9
JournalJournal of the American Chemical Society
Volume105
Issue number9
StatePublished - May 4 1983

Fingerprint

Molecular crystals
Iodides
Nickel
Iodine
Transport properties
Charge transfer
Metals
Least-Squares Analysis
Single crystals
Molecules

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

CONDUCTIVE MOLECULAR CRYSTALS. STRUCTURAL, MAGNETIC, AND CHARGE-TRANSPORT PROPERTIES OF (5,10,15,20-TETRAMETHYLPORPHYRINATO)NICKEL(II) IODIDE. / Pace, Laurel J.; Martinsen, Jens; Ulman, Abraham; Hoffman, Brian M.; Ibers, James A.

In: Journal of the American Chemical Society, Vol. 105, No. 9, 04.05.1983, p. 2612-2620.

Research output: Contribution to journalArticle

@article{d4e02cc9395c44d2b83f01240604e07b,
title = "CONDUCTIVE MOLECULAR CRYSTALS. STRUCTURAL, MAGNETIC, AND CHARGE-TRANSPORT PROPERTIES OF (5,10,15,20-TETRAMETHYLPORPHYRINATO)NICKEL(II) IODIDE.",
abstract = "(5,10,15,20-Tetramethylporphyrinato)nickel(II), Ni(tmp), has been partially oxidized by reaction with iodine. The authors report the structural, magnetic, and charge-transport properties of single crystals of the resulting compound, Ni(tmp)I. The compound crystallizes in space group D//4//h**4-P4/nnc of the tetragonal system with four formula units in a cell of dimensions a equals 16. 610 (15) A and c equals 6. 932 (7) A at 114 K. Full-matrix least-squares refinement of 69 variables gives a final value for the R index on F**2 of 0. 079 for 1418 observations. The structure consists of S//4-ruffled Ni(tmp) molecules, stacked metal-over-metal, with a Ni-Ni spacing along the stack of 3. 466 (3) A. Adjacent Ni(tmp) units in the unit cell are staggered by 37 degree . Severely disordered chains of iodine are located in channels surrounding the Ni(tmp) stacks.",
author = "Pace, {Laurel J.} and Jens Martinsen and Abraham Ulman and Hoffman, {Brian M.} and Ibers, {James A.}",
year = "1983",
month = "5",
day = "4",
language = "English (US)",
volume = "105",
pages = "2612--2620",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "9",

}

TY - JOUR

T1 - CONDUCTIVE MOLECULAR CRYSTALS. STRUCTURAL, MAGNETIC, AND CHARGE-TRANSPORT PROPERTIES OF (5,10,15,20-TETRAMETHYLPORPHYRINATO)NICKEL(II) IODIDE.

AU - Pace, Laurel J.

AU - Martinsen, Jens

AU - Ulman, Abraham

AU - Hoffman, Brian M.

AU - Ibers, James A.

PY - 1983/5/4

Y1 - 1983/5/4

N2 - (5,10,15,20-Tetramethylporphyrinato)nickel(II), Ni(tmp), has been partially oxidized by reaction with iodine. The authors report the structural, magnetic, and charge-transport properties of single crystals of the resulting compound, Ni(tmp)I. The compound crystallizes in space group D//4//h**4-P4/nnc of the tetragonal system with four formula units in a cell of dimensions a equals 16. 610 (15) A and c equals 6. 932 (7) A at 114 K. Full-matrix least-squares refinement of 69 variables gives a final value for the R index on F**2 of 0. 079 for 1418 observations. The structure consists of S//4-ruffled Ni(tmp) molecules, stacked metal-over-metal, with a Ni-Ni spacing along the stack of 3. 466 (3) A. Adjacent Ni(tmp) units in the unit cell are staggered by 37 degree . Severely disordered chains of iodine are located in channels surrounding the Ni(tmp) stacks.

AB - (5,10,15,20-Tetramethylporphyrinato)nickel(II), Ni(tmp), has been partially oxidized by reaction with iodine. The authors report the structural, magnetic, and charge-transport properties of single crystals of the resulting compound, Ni(tmp)I. The compound crystallizes in space group D//4//h**4-P4/nnc of the tetragonal system with four formula units in a cell of dimensions a equals 16. 610 (15) A and c equals 6. 932 (7) A at 114 K. Full-matrix least-squares refinement of 69 variables gives a final value for the R index on F**2 of 0. 079 for 1418 observations. The structure consists of S//4-ruffled Ni(tmp) molecules, stacked metal-over-metal, with a Ni-Ni spacing along the stack of 3. 466 (3) A. Adjacent Ni(tmp) units in the unit cell are staggered by 37 degree . Severely disordered chains of iodine are located in channels surrounding the Ni(tmp) stacks.

UR - http://www.scopus.com/inward/record.url?scp=0021094577&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0021094577&partnerID=8YFLogxK

M3 - Article

VL - 105

SP - 2612

EP - 2620

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 9

ER -