Concise synthesis of (±)-smenochromene D (= likonide B)

Brooke S. Olson, Dirk Trauner

Research output: Contribution to journalArticle

Abstract

The total synthesis of smenochromene D, an unusual ansa-terpenoid is described. The synthesis features an unprecedented macrocyclization proceeding through a biomimetic electrocyclization. The enantiomeric relationship between smenochromene D and likonide B is established.

Original languageEnglish (US)
Pages (from-to)700-702
Number of pages3
JournalSynlett
Issue number4
DOIs
StatePublished - Mar 4 2005

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Terpenes
Biomimetics
likonide B

Keywords

  • Ansa-compounds
  • Chromenes
  • Likonides
  • Macrocyclization
  • Ortho-quinone methides
  • Smenochromenes

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Concise synthesis of (±)-smenochromene D (= likonide B). / Olson, Brooke S.; Trauner, Dirk.

In: Synlett, No. 4, 04.03.2005, p. 700-702.

Research output: Contribution to journalArticle

Olson, Brooke S. ; Trauner, Dirk. / Concise synthesis of (±)-smenochromene D (= likonide B). In: Synlett. 2005 ; No. 4. pp. 700-702.
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