Coevaporated bisquaraine inverted solar cells: Enhancement due to energy transfer and open circuit voltage control

Tenghooi Goh, Jing Shun Huang, Elizabeth A. Bielinski, Bennett A. Thompson, Stephanie Tomasulo, Minjoo L. Lee, Matthew Y. Sfeir, Nilay Hazari, Andre Taylor

Research output: Contribution to journalArticle

Abstract

There is currently enormous interest in the development of small molecule organic solar cells (SMSC), as in principle, these systems offer advantages over both conventional Si photovoltaics and organic polymer solar cells. Here, we report Förster Resonance Energy Transfer (FRET) enhanced inverted SMSC fabricated by coevaporating two different squaraine donors, a symmetrical squaraine (SQ, 2,4-bis-4-[(N,N-diisobutylamino)-2,6-dihydroxyphenyl] squaraine), and an asymmetrical squaraine (ASSQ, 2,4-bis-[(N,N-diisobutylamino)-2,6-dihydroxyphenyl]-4-(4-diphenyliminio) squaraine). ASSQ absorbs blue light (λmax 540 nm) and emits from 550 nm to the near-infrared region, which overlaps with SQ absorption (λmax 690 nm). Therefore, by utilizing a thin film containing the two squaraine donors as the active layer in a SMSC, we can both broaden the photovoltaic absorption spectrum, and reduce recombination loss as a result of FRET. This strategy has resulted in SMSC with power conversion efficiencies (PCE) which are up to 46% greater than those obtained by using a single squaraine donor. Ultrafast time-resolved photoluminescence and transient absorption spectroscopy provide clear evidence of FRET between the small molecules, with a rapid energy transfer time of ∼1 ps. At optimal blending, which correlates to the highest PCE measured, the efficiency of energy transfer is as high as 85%. Furthermore, in the devices containing two different squaraine molecules, the open circuit voltage (VOC) is proportional to the fraction of the two donors in the blend, allowing us to predict the VOC as the ratio of the two donors is changed. SMSC with inverted structures also demonstrate long-term stability in ambient conditions compared to devices employing a conventional architecture.

Original languageEnglish (US)
Pages (from-to)86-95
Number of pages10
JournalACS Photonics
Volume2
Issue number1
DOIs
StatePublished - Jan 21 2015

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Energy Transfer
Open circuit voltage
open circuit voltage
Voltage control
Energy transfer
Solar cells
solar cells
energy transfer
Molecules
augmentation
molecules
volatile organic compounds
Volatile organic compounds
Conversion efficiency
Equipment and Supplies
Organic polymers
Genetic Recombination
squaraine
Absorption spectroscopy
Spectrum Analysis

Keywords

  • Förster resonance energy transfer
  • open circuit voltage control
  • photophysics
  • small-molecule solar cells
  • thermal coevaporation

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biotechnology
  • Atomic and Molecular Physics, and Optics
  • Electrical and Electronic Engineering

Cite this

Goh, T., Huang, J. S., Bielinski, E. A., Thompson, B. A., Tomasulo, S., Lee, M. L., ... Taylor, A. (2015). Coevaporated bisquaraine inverted solar cells: Enhancement due to energy transfer and open circuit voltage control. ACS Photonics, 2(1), 86-95. https://doi.org/10.1021/ph500282z

Coevaporated bisquaraine inverted solar cells : Enhancement due to energy transfer and open circuit voltage control. / Goh, Tenghooi; Huang, Jing Shun; Bielinski, Elizabeth A.; Thompson, Bennett A.; Tomasulo, Stephanie; Lee, Minjoo L.; Sfeir, Matthew Y.; Hazari, Nilay; Taylor, Andre.

In: ACS Photonics, Vol. 2, No. 1, 21.01.2015, p. 86-95.

Research output: Contribution to journalArticle

Goh, T, Huang, JS, Bielinski, EA, Thompson, BA, Tomasulo, S, Lee, ML, Sfeir, MY, Hazari, N & Taylor, A 2015, 'Coevaporated bisquaraine inverted solar cells: Enhancement due to energy transfer and open circuit voltage control', ACS Photonics, vol. 2, no. 1, pp. 86-95. https://doi.org/10.1021/ph500282z
Goh, Tenghooi ; Huang, Jing Shun ; Bielinski, Elizabeth A. ; Thompson, Bennett A. ; Tomasulo, Stephanie ; Lee, Minjoo L. ; Sfeir, Matthew Y. ; Hazari, Nilay ; Taylor, Andre. / Coevaporated bisquaraine inverted solar cells : Enhancement due to energy transfer and open circuit voltage control. In: ACS Photonics. 2015 ; Vol. 2, No. 1. pp. 86-95.
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AU - Bielinski, Elizabeth A.

AU - Thompson, Bennett A.

AU - Tomasulo, Stephanie

AU - Lee, Minjoo L.

AU - Sfeir, Matthew Y.

AU - Hazari, Nilay

AU - Taylor, Andre

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N2 - There is currently enormous interest in the development of small molecule organic solar cells (SMSC), as in principle, these systems offer advantages over both conventional Si photovoltaics and organic polymer solar cells. Here, we report Förster Resonance Energy Transfer (FRET) enhanced inverted SMSC fabricated by coevaporating two different squaraine donors, a symmetrical squaraine (SQ, 2,4-bis-4-[(N,N-diisobutylamino)-2,6-dihydroxyphenyl] squaraine), and an asymmetrical squaraine (ASSQ, 2,4-bis-[(N,N-diisobutylamino)-2,6-dihydroxyphenyl]-4-(4-diphenyliminio) squaraine). ASSQ absorbs blue light (λmax 540 nm) and emits from 550 nm to the near-infrared region, which overlaps with SQ absorption (λmax 690 nm). Therefore, by utilizing a thin film containing the two squaraine donors as the active layer in a SMSC, we can both broaden the photovoltaic absorption spectrum, and reduce recombination loss as a result of FRET. This strategy has resulted in SMSC with power conversion efficiencies (PCE) which are up to 46% greater than those obtained by using a single squaraine donor. Ultrafast time-resolved photoluminescence and transient absorption spectroscopy provide clear evidence of FRET between the small molecules, with a rapid energy transfer time of ∼1 ps. At optimal blending, which correlates to the highest PCE measured, the efficiency of energy transfer is as high as 85%. Furthermore, in the devices containing two different squaraine molecules, the open circuit voltage (VOC) is proportional to the fraction of the two donors in the blend, allowing us to predict the VOC as the ratio of the two donors is changed. SMSC with inverted structures also demonstrate long-term stability in ambient conditions compared to devices employing a conventional architecture.

AB - There is currently enormous interest in the development of small molecule organic solar cells (SMSC), as in principle, these systems offer advantages over both conventional Si photovoltaics and organic polymer solar cells. Here, we report Förster Resonance Energy Transfer (FRET) enhanced inverted SMSC fabricated by coevaporating two different squaraine donors, a symmetrical squaraine (SQ, 2,4-bis-4-[(N,N-diisobutylamino)-2,6-dihydroxyphenyl] squaraine), and an asymmetrical squaraine (ASSQ, 2,4-bis-[(N,N-diisobutylamino)-2,6-dihydroxyphenyl]-4-(4-diphenyliminio) squaraine). ASSQ absorbs blue light (λmax 540 nm) and emits from 550 nm to the near-infrared region, which overlaps with SQ absorption (λmax 690 nm). Therefore, by utilizing a thin film containing the two squaraine donors as the active layer in a SMSC, we can both broaden the photovoltaic absorption spectrum, and reduce recombination loss as a result of FRET. This strategy has resulted in SMSC with power conversion efficiencies (PCE) which are up to 46% greater than those obtained by using a single squaraine donor. Ultrafast time-resolved photoluminescence and transient absorption spectroscopy provide clear evidence of FRET between the small molecules, with a rapid energy transfer time of ∼1 ps. At optimal blending, which correlates to the highest PCE measured, the efficiency of energy transfer is as high as 85%. Furthermore, in the devices containing two different squaraine molecules, the open circuit voltage (VOC) is proportional to the fraction of the two donors in the blend, allowing us to predict the VOC as the ratio of the two donors is changed. SMSC with inverted structures also demonstrate long-term stability in ambient conditions compared to devices employing a conventional architecture.

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