Cobalt-Catalyzed Intramolecular Silylperoxidation of Unsaturated Diisopropylsilyl Ethers

Jonathan P. Oswald, Keith Woerpel

Research output: Contribution to journalArticle

Abstract

A cobalt-catalyzed intramolecular silylperoxidation reaction was developed that allows for the conversion of unsaturated diisopropylsilyl ethers to 3-sila-1,2,4-trioxepanes. Reduction of the peroxide unit of the 3-sila-1,2,4-trioxepane yields six-membered ring diisopropylsilylene acetals.

Original languageEnglish (US)
Pages (from-to)7564-7574
Number of pages11
JournalJournal of Organic Chemistry
Volume84
Issue number12
DOIs
StatePublished - Jun 21 2019

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Acetals
Ethers
Peroxides
Cobalt

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Cobalt-Catalyzed Intramolecular Silylperoxidation of Unsaturated Diisopropylsilyl Ethers. / Oswald, Jonathan P.; Woerpel, Keith.

In: Journal of Organic Chemistry, Vol. 84, No. 12, 21.06.2019, p. 7564-7574.

Research output: Contribution to journalArticle

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