Chiral studies of cooperativity in polymers

Mark M. Green, Kap Soo Cheon, Ji Woong Park

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

The ideas of stereochemistry and specifically chiral studies were applied to examine some of the disparate cooperative phenomena in polymers. In the single helical polymer chain, small chiral forces can be amplified and statistical-physical-theoretical ideas based on 1D Ising models precisely describe experimental results. In chiral studies on the constrasting disorderly cooperativity of polymer glasses and melt states, methods are developed for the time and length scale of the restrictions to motion leading to new ways of looking at the glass transition. Deviations from the transition state theory for a high barrier process are also discovered. In single chain and polymer glass studies, opportunities for the development of photonic materials arise.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherACS
Pages900-901
Number of pages2
Volume41
Edition1
StatePublished - Mar 2000
EventThe San Francisco Meeting - San Francisco, CA, USA
Duration: Mar 26 2000Mar 31 2000

Other

OtherThe San Francisco Meeting
CitySan Francisco, CA, USA
Period3/26/003/31/00

Fingerprint

Polymers
Glass
Ising model
Stereochemistry
Photonics
Glass transition

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Green, M. M., Cheon, K. S., & Park, J. W. (2000). Chiral studies of cooperativity in polymers. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (1 ed., Vol. 41, pp. 900-901). ACS.

Chiral studies of cooperativity in polymers. / Green, Mark M.; Cheon, Kap Soo; Park, Ji Woong.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 1. ed. ACS, 2000. p. 900-901.

Research output: Chapter in Book/Report/Conference proceedingChapter

Green, MM, Cheon, KS & Park, JW 2000, Chiral studies of cooperativity in polymers. in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 edn, vol. 41, ACS, pp. 900-901, The San Francisco Meeting, San Francisco, CA, USA, 3/26/00.
Green MM, Cheon KS, Park JW. Chiral studies of cooperativity in polymers. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 ed. Vol. 41. ACS. 2000. p. 900-901
Green, Mark M. ; Cheon, Kap Soo ; Park, Ji Woong. / Chiral studies of cooperativity in polymers. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 1. ed. ACS, 2000. pp. 900-901
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