Catalytically active metal oxide-supported rhodium hydride complexes

Michael Ward, Jeffrey Schwartz

Research output: Contribution to journalArticle

Abstract

Well defined metal oxide-supported rhodium hydride complexes were prepared in which the Rh is covalently anchored to the support through a rhodiumoxygen bond. The various complexes differ in their ligand environments and, as a result, exhibit markedly different behavior as olefin hydrogenation catalysts. Spectral characterization of these complexes was performed and rhodium hydrides were verified as the active species for olefin hydrogenation. Reactivity patterns for these complexes are compared with analogues in homogeneous systems.

Original languageEnglish (US)
Pages (from-to)397-407
Number of pages11
JournalJournal of Molecular Catalysis
Volume11
Issue number2-3
DOIs
StatePublished - 1981

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Rhodium
Hydrides
Olefins
Hydrogenation
Oxides
Metals
Ligands
Catalysts

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Catalytically active metal oxide-supported rhodium hydride complexes. / Ward, Michael; Schwartz, Jeffrey.

In: Journal of Molecular Catalysis, Vol. 11, No. 2-3, 1981, p. 397-407.

Research output: Contribution to journalArticle

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