Aromatic hydrocarbon derivatives of fullerences

Steven H. Hoke, Jay Molstad, Gregory L. Payne, R. J. Cotter, Bart Kahr, Dor Ben‐Amotz, R. Graham Cooks

Research output: Contribution to journalArticle

Abstract

The fullerences C60 and C70 form adducts with toluene, p‐xylene and other aromatic compounds when refluxed in these solvents in the presences of FeCl3. Benzene derivatives are produced only when bromine is also present. Mass spectra of the reaction mixtures indicate the presence of derivatives including 1:1 adducts, as well as products of multiple additions of the aromatic molecules and their dehydrogenation products. Tandem mass spectrometry provides evidence for CC bonds formation between the adducts and fullerences.

Original languageEnglish (US)
Pages (from-to)472-474
Number of pages3
JournalRapid Communications in Mass Spectrometry
Volume5
Issue number10
DOIs
StatePublished - 1991

Fingerprint

Benzene Derivatives
Aromatic Hydrocarbons
Bromine
Aromatic compounds
Toluene
Dehydrogenation
Mass spectrometry
Derivatives
Molecules

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry

Cite this

Hoke, S. H., Molstad, J., Payne, G. L., Cotter, R. J., Kahr, B., Ben‐Amotz, D., & Cooks, R. G. (1991). Aromatic hydrocarbon derivatives of fullerences. Rapid Communications in Mass Spectrometry, 5(10), 472-474. https://doi.org/10.1002/rcm.1290051010

Aromatic hydrocarbon derivatives of fullerences. / Hoke, Steven H.; Molstad, Jay; Payne, Gregory L.; Cotter, R. J.; Kahr, Bart; Ben‐Amotz, Dor; Cooks, R. Graham.

In: Rapid Communications in Mass Spectrometry, Vol. 5, No. 10, 1991, p. 472-474.

Research output: Contribution to journalArticle

Hoke, SH, Molstad, J, Payne, GL, Cotter, RJ, Kahr, B, Ben‐Amotz, D & Cooks, RG 1991, 'Aromatic hydrocarbon derivatives of fullerences', Rapid Communications in Mass Spectrometry, vol. 5, no. 10, pp. 472-474. https://doi.org/10.1002/rcm.1290051010
Hoke, Steven H. ; Molstad, Jay ; Payne, Gregory L. ; Cotter, R. J. ; Kahr, Bart ; Ben‐Amotz, Dor ; Cooks, R. Graham. / Aromatic hydrocarbon derivatives of fullerences. In: Rapid Communications in Mass Spectrometry. 1991 ; Vol. 5, No. 10. pp. 472-474.
@article{1b8c5636e835417ea2f57672aefc310a,
title = "Aromatic hydrocarbon derivatives of fullerences",
abstract = "The fullerences C60 and C70 form adducts with toluene, p‐xylene and other aromatic compounds when refluxed in these solvents in the presences of FeCl3. Benzene derivatives are produced only when bromine is also present. Mass spectra of the reaction mixtures indicate the presence of derivatives including 1:1 adducts, as well as products of multiple additions of the aromatic molecules and their dehydrogenation products. Tandem mass spectrometry provides evidence for CC bonds formation between the adducts and fullerences.",
author = "Hoke, {Steven H.} and Jay Molstad and Payne, {Gregory L.} and Cotter, {R. J.} and Bart Kahr and Dor Ben‐Amotz and Cooks, {R. Graham}",
year = "1991",
doi = "10.1002/rcm.1290051010",
language = "English (US)",
volume = "5",
pages = "472--474",
journal = "Rapid Communications in Mass Spectrometry",
issn = "0951-4198",
publisher = "John Wiley and Sons Ltd",
number = "10",

}

TY - JOUR

T1 - Aromatic hydrocarbon derivatives of fullerences

AU - Hoke, Steven H.

AU - Molstad, Jay

AU - Payne, Gregory L.

AU - Cotter, R. J.

AU - Kahr, Bart

AU - Ben‐Amotz, Dor

AU - Cooks, R. Graham

PY - 1991

Y1 - 1991

N2 - The fullerences C60 and C70 form adducts with toluene, p‐xylene and other aromatic compounds when refluxed in these solvents in the presences of FeCl3. Benzene derivatives are produced only when bromine is also present. Mass spectra of the reaction mixtures indicate the presence of derivatives including 1:1 adducts, as well as products of multiple additions of the aromatic molecules and their dehydrogenation products. Tandem mass spectrometry provides evidence for CC bonds formation between the adducts and fullerences.

AB - The fullerences C60 and C70 form adducts with toluene, p‐xylene and other aromatic compounds when refluxed in these solvents in the presences of FeCl3. Benzene derivatives are produced only when bromine is also present. Mass spectra of the reaction mixtures indicate the presence of derivatives including 1:1 adducts, as well as products of multiple additions of the aromatic molecules and their dehydrogenation products. Tandem mass spectrometry provides evidence for CC bonds formation between the adducts and fullerences.

UR - http://www.scopus.com/inward/record.url?scp=84990677982&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84990677982&partnerID=8YFLogxK

U2 - 10.1002/rcm.1290051010

DO - 10.1002/rcm.1290051010

M3 - Article

VL - 5

SP - 472

EP - 474

JO - Rapid Communications in Mass Spectrometry

JF - Rapid Communications in Mass Spectrometry

SN - 0951-4198

IS - 10

ER -