Analysis of grain structure in partially ordered block copolymers by depolarized light scattering and transmission electron microscopy

M. Y. Chang, F. M. Abuzaina, W. G. Kim, J. P. Gupton, Bruce Garetz, M. C. Newstein, N. P. Balsara, L. Yang, S. P. Gido, R. E. Cohen, Y. Boontongkong, A. Bellare

Research output: Contribution to journalArticle

Abstract

The grain structure in lamellar block copolymer samples undergoing a disorder-to-order transition was studied by a combination of depolarized light scattering (DPLS) and transmission electron microscopy (TEM). The 4-fold symmetry of the DPLS profiles indicated the presence of anisotropic grains. A pattern recognition algorithm for analyzing the TEM micrographs of samples partially filled with anisotropic, ordered grains was developed. The volume fractions of sample occupied by ordered grains determined from light scattering and electron microscopy are in reasonable agreement. Both methods indicate that, on average, the characteristic length of the grains in the direction perpendicular to the lamellar planes was a factor of 2 larger than that in the plane of the lamellae. The absolute magnitudes of grain sizes determined by light scattering are about 50% larger than those determined by microscopy.

Original languageEnglish (US)
Pages (from-to)4437-4447
Number of pages11
JournalMacromolecules
Volume35
Issue number11
DOIs
StatePublished - May 21 2002

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Crystal microstructure
Light transmission
Light scattering
Block copolymers
Transmission electron microscopy
Electron microscopy
Pattern recognition
Volume fraction
Microscopic examination

ASJC Scopus subject areas

  • Materials Chemistry

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Analysis of grain structure in partially ordered block copolymers by depolarized light scattering and transmission electron microscopy. / Chang, M. Y.; Abuzaina, F. M.; Kim, W. G.; Gupton, J. P.; Garetz, Bruce; Newstein, M. C.; Balsara, N. P.; Yang, L.; Gido, S. P.; Cohen, R. E.; Boontongkong, Y.; Bellare, A.

In: Macromolecules, Vol. 35, No. 11, 21.05.2002, p. 4437-4447.

Research output: Contribution to journalArticle

Chang, MY, Abuzaina, FM, Kim, WG, Gupton, JP, Garetz, B, Newstein, MC, Balsara, NP, Yang, L, Gido, SP, Cohen, RE, Boontongkong, Y & Bellare, A 2002, 'Analysis of grain structure in partially ordered block copolymers by depolarized light scattering and transmission electron microscopy', Macromolecules, vol. 35, no. 11, pp. 4437-4447. https://doi.org/10.1021/ma0201025
Chang, M. Y. ; Abuzaina, F. M. ; Kim, W. G. ; Gupton, J. P. ; Garetz, Bruce ; Newstein, M. C. ; Balsara, N. P. ; Yang, L. ; Gido, S. P. ; Cohen, R. E. ; Boontongkong, Y. ; Bellare, A. / Analysis of grain structure in partially ordered block copolymers by depolarized light scattering and transmission electron microscopy. In: Macromolecules. 2002 ; Vol. 35, No. 11. pp. 4437-4447.
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abstract = "The grain structure in lamellar block copolymer samples undergoing a disorder-to-order transition was studied by a combination of depolarized light scattering (DPLS) and transmission electron microscopy (TEM). The 4-fold symmetry of the DPLS profiles indicated the presence of anisotropic grains. A pattern recognition algorithm for analyzing the TEM micrographs of samples partially filled with anisotropic, ordered grains was developed. The volume fractions of sample occupied by ordered grains determined from light scattering and electron microscopy are in reasonable agreement. Both methods indicate that, on average, the characteristic length of the grains in the direction perpendicular to the lamellar planes was a factor of 2 larger than that in the plane of the lamellae. The absolute magnitudes of grain sizes determined by light scattering are about 50{\%} larger than those determined by microscopy.",
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AU - Gupton, J. P.

AU - Garetz, Bruce

AU - Newstein, M. C.

AU - Balsara, N. P.

AU - Yang, L.

AU - Gido, S. P.

AU - Cohen, R. E.

AU - Boontongkong, Y.

AU - Bellare, A.

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