Ammonium-crown ether interactions for the construction of fullerene-containing photoactive supramolecular devices

Jean François Nierengarten, Uwe Hahn, Teresa M.Figueira Duarte, François Cardinali, Nathalie Solladié, Mathieu E. Walther, Alain Van Dorsselaer, Haiko Herschbach, Emmanuelle Leize, Anne Marie Albrecht-Gary, Ali Trabolsi, Mourad Elhabiri

    Research output: Contribution to journalArticle

    Abstract

    Here, we report our recent progresses in the synthesis and the study of fullerene-containing supramolecular photoactive devices. Our approach is based on the self-assembly of C60 derivatives bearing an ammonium unit with functionalized crown ethers. The ammonium-crown ether interaction itself is weak and the Ka values are rather low when the association results only from the binding of the cationic unit with the macrocyclic component. However, when additional recognition elements are present, the stability of the complexes can be dramatically increased. This principle is illustrated with various examples of systems resulting from the self-assembly of C60-ammonium derivatives and crown ethers bearing a porphyrin or an oligophenylenevinylene chromophore. To cite this article: J.-F. Nierengarten et al., C. R. Chimie 9 (2006).

    Original languageEnglish (US)
    Pages (from-to)1022-1030
    Number of pages9
    JournalComptes Rendus Chimie
    Volume9
    Issue number7-8
    DOIs
    StatePublished - Jul 1 2006

    Fingerprint

    Crown Ethers
    Crown ethers
    Bearings (structural)
    Ammonium Compounds
    Self assembly
    Fullerenes
    Derivatives
    Porphyrins
    Chromophores
    Association reactions

    Keywords

    • Binding studies
    • Conjugated systems
    • Crown ether
    • Fullerene
    • Porphyrin
    • Supramolecular chemistry

    ASJC Scopus subject areas

    • Chemistry(all)
    • Chemical Engineering(all)

    Cite this

    Nierengarten, J. F., Hahn, U., Duarte, T. M. F., Cardinali, F., Solladié, N., Walther, M. E., ... Elhabiri, M. (2006). Ammonium-crown ether interactions for the construction of fullerene-containing photoactive supramolecular devices. Comptes Rendus Chimie, 9(7-8), 1022-1030. https://doi.org/10.1016/j.crci.2005.11.005

    Ammonium-crown ether interactions for the construction of fullerene-containing photoactive supramolecular devices. / Nierengarten, Jean François; Hahn, Uwe; Duarte, Teresa M.Figueira; Cardinali, François; Solladié, Nathalie; Walther, Mathieu E.; Van Dorsselaer, Alain; Herschbach, Haiko; Leize, Emmanuelle; Albrecht-Gary, Anne Marie; Trabolsi, Ali; Elhabiri, Mourad.

    In: Comptes Rendus Chimie, Vol. 9, No. 7-8, 01.07.2006, p. 1022-1030.

    Research output: Contribution to journalArticle

    Nierengarten, JF, Hahn, U, Duarte, TMF, Cardinali, F, Solladié, N, Walther, ME, Van Dorsselaer, A, Herschbach, H, Leize, E, Albrecht-Gary, AM, Trabolsi, A & Elhabiri, M 2006, 'Ammonium-crown ether interactions for the construction of fullerene-containing photoactive supramolecular devices', Comptes Rendus Chimie, vol. 9, no. 7-8, pp. 1022-1030. https://doi.org/10.1016/j.crci.2005.11.005
    Nierengarten, Jean François ; Hahn, Uwe ; Duarte, Teresa M.Figueira ; Cardinali, François ; Solladié, Nathalie ; Walther, Mathieu E. ; Van Dorsselaer, Alain ; Herschbach, Haiko ; Leize, Emmanuelle ; Albrecht-Gary, Anne Marie ; Trabolsi, Ali ; Elhabiri, Mourad. / Ammonium-crown ether interactions for the construction of fullerene-containing photoactive supramolecular devices. In: Comptes Rendus Chimie. 2006 ; Vol. 9, No. 7-8. pp. 1022-1030.
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