Absolute configuration and optical rotatory power of sulfoxides and sulfinate esters

Kurt Mislow, Mark M. Green, Peter Laur, Joseph T. Melillo, Todd Simmons, Andrew L. Ternay

Research output: Contribution to journalArticle

Abstract

Evidence is presented which firmly establishes the absolute configuration of a number of sulfinate esters and sulfoxides. Previous speculations which bear on the problem of the absolute configuration of optically active sulfoxides and sulfinate esters are critically examined. The optical rotatory dispersion of sulfoxides and sulfinate esters has been investigated. The observed Cotton effects are for the most part conveniently categorized according to the previously adopted viewpoint of inherently dissymmetric and asymmetrically perturbed symmetric chromophores.

Original languageEnglish (US)
Pages (from-to)1958-1976
Number of pages19
JournalJournal of the American Chemical Society
Volume87
Issue number9
StatePublished - 1965

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Sulfoxides
Esters
Optical Rotatory Dispersion
Chromophores
Cotton

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Mislow, K., Green, M. M., Laur, P., Melillo, J. T., Simmons, T., & Ternay, A. L. (1965). Absolute configuration and optical rotatory power of sulfoxides and sulfinate esters. Journal of the American Chemical Society, 87(9), 1958-1976.

Absolute configuration and optical rotatory power of sulfoxides and sulfinate esters. / Mislow, Kurt; Green, Mark M.; Laur, Peter; Melillo, Joseph T.; Simmons, Todd; Ternay, Andrew L.

In: Journal of the American Chemical Society, Vol. 87, No. 9, 1965, p. 1958-1976.

Research output: Contribution to journalArticle

Mislow, K, Green, MM, Laur, P, Melillo, JT, Simmons, T & Ternay, AL 1965, 'Absolute configuration and optical rotatory power of sulfoxides and sulfinate esters', Journal of the American Chemical Society, vol. 87, no. 9, pp. 1958-1976.
Mislow K, Green MM, Laur P, Melillo JT, Simmons T, Ternay AL. Absolute configuration and optical rotatory power of sulfoxides and sulfinate esters. Journal of the American Chemical Society. 1965;87(9):1958-1976.
Mislow, Kurt ; Green, Mark M. ; Laur, Peter ; Melillo, Joseph T. ; Simmons, Todd ; Ternay, Andrew L. / Absolute configuration and optical rotatory power of sulfoxides and sulfinate esters. In: Journal of the American Chemical Society. 1965 ; Vol. 87, No. 9. pp. 1958-1976.
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