A stable tetraalkyl complex of nickel(IV)

Matthew Carnes, Daniela Buccella, Judy Y C Chen, Arthur P. Ramirez, Nicholas J. Turro, Colin Nuckolls, Michael Steigerwald

Research output: Contribution to journalArticle

Abstract

Ni takes a load off: Nickel(0) and a strained alkene react to form a stable tris(alkene) complex, which eliminates the corresponding trans,trans,trans- cyclobutane upon heating. A higher proportion of alkene to Ni0 precursor yielded the first all-alkyl complex of nickel(IV) (see structure; Ni: green). These reactions, which involve ligand coupling, are driven by relief of ring strain in the alkene. (Figure Presented).

Original languageEnglish (US)
Pages (from-to)290-294
Number of pages5
JournalAngewandte Chemie - International Edition
Volume48
Issue number2
DOIs
StatePublished - Jan 2 2009

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Alkenes
Nickel
Olefins
Cyclobutanes
Ligands
Heating

Keywords

  • Alkene ligands
  • Cycloaddition
  • Nickel
  • Organometallic compounds

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Carnes, M., Buccella, D., Chen, J. Y. C., Ramirez, A. P., Turro, N. J., Nuckolls, C., & Steigerwald, M. (2009). A stable tetraalkyl complex of nickel(IV). Angewandte Chemie - International Edition, 48(2), 290-294. https://doi.org/10.1002/anie.200804435

A stable tetraalkyl complex of nickel(IV). / Carnes, Matthew; Buccella, Daniela; Chen, Judy Y C; Ramirez, Arthur P.; Turro, Nicholas J.; Nuckolls, Colin; Steigerwald, Michael.

In: Angewandte Chemie - International Edition, Vol. 48, No. 2, 02.01.2009, p. 290-294.

Research output: Contribution to journalArticle

Carnes, M, Buccella, D, Chen, JYC, Ramirez, AP, Turro, NJ, Nuckolls, C & Steigerwald, M 2009, 'A stable tetraalkyl complex of nickel(IV)', Angewandte Chemie - International Edition, vol. 48, no. 2, pp. 290-294. https://doi.org/10.1002/anie.200804435
Carnes M, Buccella D, Chen JYC, Ramirez AP, Turro NJ, Nuckolls C et al. A stable tetraalkyl complex of nickel(IV). Angewandte Chemie - International Edition. 2009 Jan 2;48(2):290-294. https://doi.org/10.1002/anie.200804435
Carnes, Matthew ; Buccella, Daniela ; Chen, Judy Y C ; Ramirez, Arthur P. ; Turro, Nicholas J. ; Nuckolls, Colin ; Steigerwald, Michael. / A stable tetraalkyl complex of nickel(IV). In: Angewandte Chemie - International Edition. 2009 ; Vol. 48, No. 2. pp. 290-294.
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