A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor

Fettah Ajamaa, Anne Marie Albrecht-Gary, Juan Luis Delgado De La Cruz, Mourad Elhabiri, Jean François Nierengarten, Nathalie Solladié, Ali Trabolsi, Maxence Urbani

Research output: Contribution to journalArticle

Abstract

A fullerene derivative bearing two pyridine subunits has been designed to allow assembly with a bis-Zn(II)-phorphyrin receptor with two equivalent Zn binding sites separated by about 20 Å. Owing to the complementarity between the bis-Zn(II)-porphyrin receptor and a fullerene ligand bearing two pyridine substituents, the substrate can be clicked on the ditopic receptor, thus leading to a stable non-covalent macrocyclic 1:1 complex.

Original languageEnglish (US)
Pages (from-to)1337-1345
Number of pages9
JournalJournal of Porphyrins and Phthalocyanines
Volume10
Issue number12
DOIs
StatePublished - Jan 1 2006

Fingerprint

Bearings (structural)
Fullerenes
Porphyrins
Ligands
Binding Sites
Derivatives
Substrates
pyridine

Keywords

  • Binding studies
  • Fullerene
  • Porphyrin
  • Supramolecular chemistry

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Ajamaa, F., Albrecht-Gary, A. M., De La Cruz, J. L. D., Elhabiri, M., Nierengarten, J. F., Solladié, N., ... Urbani, M. (2006). A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor. Journal of Porphyrins and Phthalocyanines, 10(12), 1337-1345. https://doi.org/10.1142/S1088424606000715

A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor. / Ajamaa, Fettah; Albrecht-Gary, Anne Marie; De La Cruz, Juan Luis Delgado; Elhabiri, Mourad; Nierengarten, Jean François; Solladié, Nathalie; Trabolsi, Ali; Urbani, Maxence.

In: Journal of Porphyrins and Phthalocyanines, Vol. 10, No. 12, 01.01.2006, p. 1337-1345.

Research output: Contribution to journalArticle

Ajamaa, Fettah ; Albrecht-Gary, Anne Marie ; De La Cruz, Juan Luis Delgado ; Elhabiri, Mourad ; Nierengarten, Jean François ; Solladié, Nathalie ; Trabolsi, Ali ; Urbani, Maxence. / A macrocyclic supramolecular complex obtained from a fullerene ligand bearing two pyridine substituents and a bis-Zn(II)-porphyrin receptor. In: Journal of Porphyrins and Phthalocyanines. 2006 ; Vol. 10, No. 12. pp. 1337-1345.
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