8.30 Spectroscopic Analysis: Chiroptical Sensors

James Canary, Z. Dai, S. Mortezaei

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Chiroptical sensors have been designed that detect a multitude of different analytes with a high level of sensitivity. A wide range of scaffolds have been used that respond to metals, small molecules, anions, and other analytes. Not only have chiroptical systems been used to detect the presence of analytes but also other properties such as oxidation state and other physical phenomena that influence the helicity and conformation of molecules and materials. The primary mode of detection for the reviewed chiroptical sensors is circular dichroism, but other techniques have been explored recently. Recently, high-throughput screening methods have been used to evaluate sensors for the determination of enantiomeric excess. With the development of solid-state chiroptical sensors still at early stages of development, this review mainly covers liquid-based techniques.

Original languageEnglish (US)
Title of host publicationComprehensive Chirality
PublisherElsevier Ltd
Pages600-624
Number of pages25
Volume8
ISBN (Print)9780080951683
DOIs
StatePublished - Sep 2012

Fingerprint

Spectroscopic analysis
Sensors
Solid-state sensors
Molecules
Scaffolds
Anions
Conformations
Screening
Metals
Throughput
Oxidation
Liquids

Keywords

  • Chiral recognition
  • Chirality
  • Chiroptical switches
  • Circular dichroism
  • Enantiomer excess
  • Fluorescent sensors
  • Sensor
  • Supramolecular chirality

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Canary, J., Dai, Z., & Mortezaei, S. (2012). 8.30 Spectroscopic Analysis: Chiroptical Sensors. In Comprehensive Chirality (Vol. 8, pp. 600-624). Elsevier Ltd. https://doi.org/10.1016/B978-0-08-095167-6.00850-8

8.30 Spectroscopic Analysis : Chiroptical Sensors. / Canary, James; Dai, Z.; Mortezaei, S.

Comprehensive Chirality. Vol. 8 Elsevier Ltd, 2012. p. 600-624.

Research output: Chapter in Book/Report/Conference proceedingChapter

Canary, J, Dai, Z & Mortezaei, S 2012, 8.30 Spectroscopic Analysis: Chiroptical Sensors. in Comprehensive Chirality. vol. 8, Elsevier Ltd, pp. 600-624. https://doi.org/10.1016/B978-0-08-095167-6.00850-8
Canary J, Dai Z, Mortezaei S. 8.30 Spectroscopic Analysis: Chiroptical Sensors. In Comprehensive Chirality. Vol. 8. Elsevier Ltd. 2012. p. 600-624 https://doi.org/10.1016/B978-0-08-095167-6.00850-8
Canary, James ; Dai, Z. ; Mortezaei, S. / 8.30 Spectroscopic Analysis : Chiroptical Sensors. Comprehensive Chirality. Vol. 8 Elsevier Ltd, 2012. pp. 600-624
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