1-Phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives as versatile hydrogen-bonding motifs for the formation of one-, two- and three-dimensional networks in the solid state

Qing Lin, Steven J. Geib, Andrew Hamilton

Research output: Contribution to journalArticle

Abstract

A series of 1-phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives were prepared and their solid state structures were investigated. Small structural changes in the monomeric subunit can lead to the formation of one-dimensional linear ribbons, two-dimensional sheets and three-dimensional networks. In each case a consistent feature of the solid state structures is the formation of bidentate hydrogen bonded contacts between the 2,5-carboxylic acid groups on adjacent pyrrole subunits. The exact nature of the crystal packing is strongly influenced by the substitution on the phenyl ring.

Original languageEnglish (US)
Pages (from-to)2109-2116
Number of pages8
JournalJournal of the Chemical Society. Perkin Transactions 2
Issue number10
StatePublished - Oct 1998

Fingerprint

Dicarboxylic Acids
Pyrroles
Hydrogen bonds
Derivatives
Carboxylic Acids
Hydrogen
Substitution reactions
Crystals

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

@article{d9d571474bfe495cb4569baf66d26c9f,
title = "1-Phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives as versatile hydrogen-bonding motifs for the formation of one-, two- and three-dimensional networks in the solid state",
abstract = "A series of 1-phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives were prepared and their solid state structures were investigated. Small structural changes in the monomeric subunit can lead to the formation of one-dimensional linear ribbons, two-dimensional sheets and three-dimensional networks. In each case a consistent feature of the solid state structures is the formation of bidentate hydrogen bonded contacts between the 2,5-carboxylic acid groups on adjacent pyrrole subunits. The exact nature of the crystal packing is strongly influenced by the substitution on the phenyl ring.",
author = "Qing Lin and Geib, {Steven J.} and Andrew Hamilton",
year = "1998",
month = "10",
language = "English (US)",
pages = "2109--2116",
journal = "Journal of the Chemical Society, Perkin Transactions 2",
issn = "1470-1820",
publisher = "Chemical Society",
number = "10",

}

TY - JOUR

T1 - 1-Phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives as versatile hydrogen-bonding motifs for the formation of one-, two- and three-dimensional networks in the solid state

AU - Lin, Qing

AU - Geib, Steven J.

AU - Hamilton, Andrew

PY - 1998/10

Y1 - 1998/10

N2 - A series of 1-phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives were prepared and their solid state structures were investigated. Small structural changes in the monomeric subunit can lead to the formation of one-dimensional linear ribbons, two-dimensional sheets and three-dimensional networks. In each case a consistent feature of the solid state structures is the formation of bidentate hydrogen bonded contacts between the 2,5-carboxylic acid groups on adjacent pyrrole subunits. The exact nature of the crystal packing is strongly influenced by the substitution on the phenyl ring.

AB - A series of 1-phenyl-1H-pyrrole-2,5-dicarboxylic acid derivatives were prepared and their solid state structures were investigated. Small structural changes in the monomeric subunit can lead to the formation of one-dimensional linear ribbons, two-dimensional sheets and three-dimensional networks. In each case a consistent feature of the solid state structures is the formation of bidentate hydrogen bonded contacts between the 2,5-carboxylic acid groups on adjacent pyrrole subunits. The exact nature of the crystal packing is strongly influenced by the substitution on the phenyl ring.

UR - http://www.scopus.com/inward/record.url?scp=0000570064&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000570064&partnerID=8YFLogxK

M3 - Article

SP - 2109

EP - 2116

JO - Journal of the Chemical Society, Perkin Transactions 2

JF - Journal of the Chemical Society, Perkin Transactions 2

SN - 1470-1820

IS - 10

ER -